Abstract
Tungsten and helium isotope ratios in lavas derived from deeply rooted mantle plumes are tracers of lower mantle compositional heterogeneity or core-mantle exchange. We measured the tungsten isotopic compositions of lavas with exceptionally high-He-3/He-4 ratios that erupted above the head of the Iceland plume on Baffin Island. These lavas have W-182/W-184 ratios that are indistinguishable from the convecting upper mantle, unlike younger lavas in Iceland that have lower W-182/W-184 ratios. This implies that only the Iceland plume tail was infused with low W-182/W-184 material, likely from the core. If high-He-3/He-4 helium also comes from the core, then diffusion across the core-mantle boundary may stratify plume-source mantle domains, with elevated He-3/He-4 travelling farther into the lower mantle than W-182/W-184 anomalies. Over Earth history, tungsten diffusion from the core can explain the decline of W-182/W-184 in the convecting mantle. We speculate that the uneven pace of this decline corresponds with evolving lower mantle dynamics.