Molecular emission is used to investigate both the physical and chemical properties of protoplanetary disks. Therefore, to derive disk properties accurately, we need a thorough understanding of the behavior of the molecular probes upon which we rely. Here we investigate how the molecular line emission of N2H+, HCO+, HCN, and C18O compare to other measured quantities in a set of 20 protoplanetary disks. Overall, we find positive correlations between multiple line fluxes and the disk dust mass and radius. We also generally find strong positive correlations between the line fluxes of different molecular species. However, some disks do show noticeable differences in the relative fluxes of N2H+, HCO+, HCN, and C18O. These differences occur even within a single star-forming region. This results in a potentially large range of different disk masses and chemical compositions for systems of similar age and birth environment. While we make preliminary comparisons of molecular fluxes across different star-forming regions, more complete and uniform samples are needed in the future to search for trends with birth environment or age.

The chemical composition of an extrasolar planet is fundamental to its formation, evolution, and habitability. In this study, we explore a new way to measure the chemical composition of the building blocks of extrasolar planets by measuring the gas composition of the disrupted planetesimals around white dwarf stars. As a first attempt, we used the photoionization code Cloudy to model the circumstellar gas emission around white dwarf Gaia J0611-6931 under some simplified assumptions. We found that most of the emission lines are saturated, and the line ratios approach the ratios of thermal emission; therefore, only lower limits to the number density can be derived. Silicon is the best-constrained element in the circumstellar gas, and we derived a lower limit of 10(10.3) cm(-3). In addition, we placed a lower limit on the total amount of gas to be 1.8 x 10(19) g. Further study is needed to better constrain the parameters of the gas disk and connect it to other white dwarfs with circumstellar gas absorption.

Seismic and mineralogical studies have suggested regions at Earth's core-mantle boundary may be highly enriched in FeO, reported to exhibit metallic behavior at extreme pressure-temperature (P-T) conditions. However, underlying electronic processes in FeO remain poorly understood. Here we explore the electronic structure of B1-FeO at extreme conditions with large-scale theoretical modeling using state-of-the-art embedded dynamical mean field theory (eDMFT). Fine sampling of the phase diagram reveals that, instead of sharp metallization, compression of FeO at high temperatures induces a gradual orbitally selective insulator-metal transition. Specifically, at P-T conditions of the lower mantle, FeO exists in an intermediate quantum critical state, characteristic of strongly correlated electronic matter. Transport in this regime, distinct from insulating or metallic behavior, is marked by incoherent diffusion of electrons in the conducting t2g orbital and a band gap in the eg orbital, resulting in moderate electrical conductivity (~105 S/m) with modest P-T dependence as observed in experiments. Enrichment of solid FeO can thus provide a unifying explanation for independent observations of low seismic velocities and elevated electrical conductivities in heterogeneities at Earth's mantle base.

Context. A spatially resoved circumstellar disk spectrum and composition can provide valuable insights into the bulk composition of forming planets and into the mineralogical signatures that emerge during and after planet formation.

Supermassive black hole (SMBH) masses can be measured by observing their dynamical effects on tracers, such as molecular gas. We present high angular resolution Atacama Large Millimeter/submillimeter Array observations of the (CO)-C-12(2-1) line emission of the early-type galaxies (ETGs) NGC 1684 and NGC 0997, obtained as part of the MASSIVE survey, a volume-limited integral-field spectroscopic study of the most massive local ETGs. NGC 1684 has a regularly rotating central molecular gas disc, with a spatial extent of approximate to 6 arcsec (approximate to 1.8 kpc) in radius and a central hole slightly larger than the expected SMBH sphere of influence. We forward model the data cube in a Bayesian framework with the Kinematic Molecular Simulation (KinMS) code and infer a SMBH mass of $1.40<^>{+0.44}_{-0.39}\times 10<^>9$ M-circle dot (3 sigma confidence interval) and an F110W-filter stellar mass-to-light ratio of (2.50 +/- 0.05) M-circle dot/L-circle dot,L- F110W. NGC 0997 has a regularly rotating central molecular gas disc, with a spatial extent of approximate to 5 arcsec (approximate to 2.2 kpc) in radius and a partially filled central hole much larger than the expected SMBH sphere of influence, thus preventing a robust SMBH mass determination. With the same modelling method, we nevertheless constrain the SMBH mass to be in the range 4.0 x 10(7)-1.8 x 10(9) M-circle dot and the F160W-filter stellar mass-to-light ratio to be (1.52 +/- 0.11) M-circle dot/L-circle dot,L- F160W. Both SMBH masses are consistent with the SMBH mass-stellar velocity dispersion (M-BH-sigma(e)) relation, suggesting that the overmassive SMBHs present in other very massive ETGs are fairly uncommon.

We present results from the Quasar hosts Unveiled by high Angular Resolution Techniques survey studying the circumgalactic medium (CGM) by observing rest-frame UV emission lines Ly alpha, C iv, and He ii around two radio-loud quasars, 3C 9 (z = 2.02) and 4C 05.84 (z = 2.32), using the Keck Cosmic Web Imager. We detect large-scale Ly alpha nebulae around both quasars with projected diameters similar to 100 kpc, with spatially resolved, embedded 15-30 kpc He ii and C iv nebulae around both quasars as well as kinematically distinct He ii and C iv nebulae at a physical separation of similar to 15 kpc from both quasars. Observations of H alpha, H beta, and [O iii] emission using Keck MOSFIRE spectroscopically confirm that the Ly alpha nebulae extend to companion galaxies and that these quasars are in a protogroup/protocluster environment. We confirm that the He ii and C iv emission is kinematically and spatially coincident with the companion galaxies. We estimate the virial masses of the companion galaxies, their metallicities, and star formation rates, and investigate the sources of ionization. We measure the dynamical mass of the host dark matter halos and estimate that the dark matter halos of these systems will grow to a mass of 2 x 1014 M circle dot (3C 9) and 2 x 1013 M circle dot (4C 05.84) by z = 0. The combined CGM and companion galaxies observations indicate Ly alpha substructure can indicate the presence of companion galaxies in the CGM.

"Changing-look" active galactic nuclei (CL-AGNs) challenge our basic ideas about the physics of accretion flows and circumnuclear gas around supermassive black holes. Using first-year Sloan Digital Sky Survey V (SDSS-V) repeated spectroscopy of nearly 29,000 previously known active galactic nuclei (AGNs), combined with dedicated follow-up spectroscopy, and publicly available optical light curves, we have identified 116 CL-AGNs where (at least) one broad emission line has essentially (dis-)appeared, as well as 88 other extremely variable systems. Our CL-AGN sample, with 107 newly identified cases, is the largest reported to date, and includes similar to 0.4% of the AGNs reobserved in first-year SDSS-V operations. Among our CL-AGNs, 67% exhibit dimming while 33% exhibit brightening. Our sample probes extreme AGN spectral variability on months to decades timescales, including some cases of recurring transitions on surprisingly short timescales (less than or similar to 2 months in the rest frame). We find that CL events are preferentially found in lower-Eddington-ratio (f Edd) systems: Our CL-AGNs have a f Edd distribution that significantly differs from that of a carefully constructed, redshift- and luminosity-matched control sample (Anderson-Darling test yielding p AD approximate to 6 x 10-5; median f Edd approximate to 0.025 versus 0.043). This preference for low f Edd strengthens previous findings of higher CL-AGN incidence at lower f Edd, found in smaller samples. Finally, we show that the broad Mg ii emission line in our CL-AGN sample tends to vary significantly less than the broad H beta emission line. Our large CL-AGN sample demonstrates the advantages and challenges in using multi-epoch spectroscopy from large surveys to study extreme AGN variability and physics.

The Hercules ultrafaint dwarf galaxy (UFD) has long been hypothesized to be tidally disrupting, yet no conclusive evidence has been found for tidal disruption owing partly to difficulties in identifying Hercules member stars. In this work, we present a homogeneous reanalysis of new and existing observations of Hercules, including the detection of a new potential member star located similar to 1 degrees (similar to 1.7 kpc) west of the center of the system. In addition to measuring the line-of-sight velocity gradient, we compare predictions from dynamical models of stream formation to these observations. We report an updated velocity dispersion measurement based on 28 stars, 1.9(-0.6)(+0.6) km s(-1), which is significantly lower than previous measurements. We find that the line-of-sight velocity gradient is 1.8(-1.8)(+1.8) km s(-1) kpc along the major axis of Hercules, consistent with zero within 1 sigma. Our dynamical models of stream formation, on the other hand, can reproduce the morphology of the Hercules UFD, specifically the misalignment between the elongation and the orbital motion direction. Additionally, these dynamical models indicate that any radial velocity gradient from tidal disruption would be too small, 0.00(-0.91)(+0.97) km s(-1 )kpc, to be detectable with current sample sizes. Combined with our analysis of the tidal radius evolution of the system as a function of its orbital phase, we argue that it is likely that Hercules is indeed currently undergoing tidal disruption in its extended stellar halo with a line-of-sight velocity gradient too small to be detected with current observational data sets..

The aluminous calcium-ferrite type phase (CF) and new aluminous phase (NAL) are thought to hold the excess alumina produced by the decomposition of garnet in MORB compositions in the lower mantle. The respective stabilities of CF and NAL in the nepheline-spinel binary (NaAlSiO4-MgAl2O4) are well established. However with the addition of further components the phase relations at lower mantle conditions remain unclear. Here we investigate a range of compositions around the nepheline apex of the nepheline-kalsilite-spinel compositional join (NaAlSiO4-KAlSiO4-MgAl2O4) at 28-78GPa and 2000K. Our experiments indicate that even small amounts of a kalsilite (KAlSiO4) component dramatically impact phase relations. We find NAL to be stable up to at least 71GPa in potassium-bearing compositions. This demonstrates the stabilizing effect of potassium on NAL, because NAL is not observed at pressures above 48GPa on the nepheline-spinel binary. We also observe a broadening of the CF stability field to incorporate larger amounts of potassium with increasing pressure. For pressures below 50GPa only minor amounts (<0.011(1)KK+Na+Mg) of potassium are soluble in CF, whereas at 68GPa, we find a solubility in CF of at least 0.088(3)KK+Na+Mg. This indicates that CF and NAL are suitable hosts of the alkali content of MORB compositions at lower mantle conditions. For sedimentary compositions at lower mantle pressures, we expect K-Hollandite to be stable in addition to CF and NAL for pressures of 28-48GPa, based on our simplified compositions.

Seismic tomography has shown that the shear wave velocities (Vs) under continents, especially under cratons, are extremely fast at 100-200 km depth, which is difficult to explain by low temperatures or high Mg#. Alternatively, delaminated eclogitic lower continental crust has been proposed to account for these fast seismic anomalies. However, the thermoelastic properties of jadeite which constitutes up to 60-80 mol% of clinopyroxene in the potentially delaminated lower continental crust are not well constrained. In this study, we measured the single-crystal elasticity of jadeite by Brillouin spectroscopy under simultaneous high pressure and temperature conditions for the first time. We found that the temperature dependence of Vs of jadeite is extremely small if not negligible. The seismic velocities of the potentially delaminated lower continental crusts were subsequently modeled and found to match the widely observed fast seismic anomalies under cratons between 100 and 200 km depth.