Alternative technologies are required in order to meet a worldwide demand for clean non-polluting energy sources. Thermoelectric generators, which generate electricity from heat in a compact and reliable manner, are potential devices for waste heat recovery. However, thermoelectric performance, as encapsulated by the figure of merit ZT, has remained at around 1.0 at room temperature, which has limited practical applications. Here, we study the effects of pressure on ZT in Cr-doped PbSe, which has a maximum ZT of less than 1.0 at a temperature of about 700 K. By applying external pressure using a diamond anvil cell, we obtained a room-temperature ZT value of about 1.7. From thermoelectric, magnetoresistance and Raman measurements, as well as density functional theory calculations, a pressure-driven topological phase transition is found to enable this enhancement. Experiments also support the appearance of a topological crystalline insulator after the transition. These findings point to the possibility of using compression to increase not just ZT in existing thermoelectric materials, but also the possibility of realizing topological crystalline insulators.

The small class of known stars with unusually warm, dusty debris disks is a key sample to probe in order to understand cascade models and the extreme collisions that likely lead to the final configurations of planetary systems. Because of its extreme dustiness and small radius, the disk of BD +20 307 has a short predicted collision time and is therefore an interesting target in which to look for changes in dust quantity and composition over time. To compare with previous ground and Spitzer Space Telescope data, Stratospheric Observatory for Infrared Astronomy (SOFIA) photometry and spectroscopy were obtained. The system's 8.8-12.5 mu m infrared emission increased by 10 +/- 2% over nine years between the SOFIA and earlier Spitzer measurements. In addition to an overall increase in infrared excess, there is a suggestion of a greater increase in flux at shorter wavelengths (less than 10.6 mu m) compared to longer wavelengths (greater than 10.6 mu m). Steady-state collisional cascade models cannot explain the increase in BD +20 307's disk flux over such short timescales. A catastrophic collision between planetary-scale bodies is still the most likely origin for the system's extreme dust; however, the cause for its recent variation requires further investigation.

We performed Raman and infrared (IR) spectroscopy measurements of hydrogen at 295 K up to 280 GPa at an IR synchrotron facility of the Shanghai Synchrotron Radiation Facility (SSRF). To reach the highest pressure, hydrogen was loaded into toroidal diamond anvils with 30-mu m central culet. The intermolecular coupling has been determined by concomitant measurements of the IR and Raman vibron modes. In phase IV, we find that the intermolecular coupling is much stronger in the graphenelike layer (G layer) of elongated molecules compared to the Br2-like layer (B layer) of shortened molecules and it increases with pressure much faster in the G layer compared to the B layer. These heterogeneous lattice dynamical properties are unique features of highly fluxional hydrogen phase IV.

The fate of subducted carbonates in the lower mantle and at the core-mantle boundary was modelled via experiments in the MgCO3-Fe-0 system at 70-150 GPa and 800-2600 K in a laser-heated diamond anvil cell. Using in situ synchrotron X-ray diffraction and ex situ transmission electron microscopy we show that the reduction of Mg-carbonate can be exemplified by: 6MgCO(3) + 19Fe = 8FeO +10(Mg0.6Fe0.4)O + Fe7C3 + 3C. The presented results suggest that the interaction of carbonates with Fe-0 or Fe-0-bearing rocks can produce Fe-carbide and diamond, which can accumulate in the D '' region, depending on its carbon to Fe ratio. Due to the sluggish kinetics of the transformation, diamond can remain metastable at the core-mantle boundary (CMB) unless it is in a direct contact with Fe-metal. In addition, it can be remobilized by redox melting accompanying the generation of mantle plumes. (C) 2019, China University of Geosciences (Beijing) and Peking University. Production and hosting by Elsevier B.V.

Young, low-mass stars in the solar neighborhood are vital for completing the mass function for nearby, young coeval groups, establishing a more complete census for evolutionary studies, and providing targets for direct-imaging exoplanet and/or disk studies. We present properties derived from high-resolution optical spectra for 336 candidate young nearby, low-mass stars. These include measurements of radial velocities and age diagnostics such as H alpha and Li lambda 6707 equivalent widths. Combining our radial velocities with astrometry from Gaia DR2, we provide full 3D kinematics for the entire sample. We combine the measured spectroscopic youth information with additional age diagnostics (e.g., X-ray and UV fluxes, color-magnitude diagram positions) and kinematics to evaluate potential membership in nearby, young moving groups and associations. We identify 77 objects in our sample as bona fide members of 10 different moving groups, 14 of which are completely new members or have had their group membership reassigned. We also reject 44 previously proposed candidate moving group members. Furthermore, we have newly identified or confirmed the youth of numerous additional stars that do not belong to any currently known group and find 69 comoving systems using Gaia DR2 astrometry. We also find evidence that the Carina association is younger than previously thought, with an age similar to the beta Pictoris moving group (similar to 22 Myr).

We present observations of the HD 15115 debris disk from the Atacama Large Millimeter/submillimeter Array (ALMA) at 1.3 mm that capture this intriguing system with the highest resolution (0 ''.6 or 29 au) at millimeter wavelengths to date. This new ALMA image shows evidence for two rings in the disk separated by a cleared gap. By fitting models directly to the observed visibilities within a Markov Chain Monte Carlo framework, we are able to characterize the millimeter continuum emission and place robust constraints on the disk structure and geometry. In the best-fit model of a power-law disk with a Gaussian gap, the disk inner and outer edges are at 43.9 +/- 5.8 au (0 ''.89 +/- 0 ''.12) and 92.2 +/- 2.4 au (1 ''.88 +/- 0 ''.49), respectively, with a gap located at 58.9 +/- 4.5 au (1 ''.2 +/- 0 ''.10) with a fractional depth of 0.88 +/- 0.10 and a width of 13.8 +/- 5.6 au (0 ''.28 +/- 0 ''.11). Because we do not see any evidence at millimeter wavelengths for the dramatic east-west asymmetry seen in scattered light, we conclude that this feature most likely results from a mechanism that only affects small grains. Using dynamical modeling and our constraints on the gap properties, we are able to estimate a mass for the possible planet sculpting the gap to be 0.16 +/- 0.06 M-Jup.

Both the vibrational and electrical transport properties of 2H-TaS2 have been investigated at high pressures and low temperatures. The collapse of the charge-density-wave order at pressures above 7.3 GPa has been verified by Raman scattering, resistivity, and Hall coefficient measurements. For pressures above the critical pressure of 7.3 GPa, the superconducting transition temperature continues to increase and reaches its maximum value at 11.5 GPa, suggesting that it is not a simple competition between the charge-density-wave order and superconductivity. Through the standard resistivity fit in the normal state, the decline of the superconducting transition temperature with increasing pressure up to 47.0 GPa is due to the decrease of interaction strength and the increase of the impurity scattering. These results are very important in understanding the superconducting mechanism of transition-metal dichalcogenides.

Hydrogen is expected to display remarkable properties under extreme pressures and temperatures stemming from its low mass and thus propensity to quantum phenomena. Exploring such phenomena remains very challenging even though there was a tremendous technical progress both in experimental and theoretical techniques since the last comprehensive review (McMahon et al.) was published in 2012. Raman and optical spectroscopy experiments including infrared have been extended to cover a broad range of pressures and temperatures (P-T) probing phase stability and optical properties at these conditions. Novel pulsed laser heating and toroidal diamond anvil techniques together with diamond anvil protecting layers drastically improved the capabilities of static compression methods. The electrical conductivity measurements have been also performed to much higher than previously pressures and extended to low temperatures. The dynamic compression techniques have been dramatically improved recently enabling ramp isentropic compression that allows probing a wide range of P-T thermodynamic pathways. In addition, new theoretical methods have been developed beyond a common DFT theory, which make them predictive and in better agreement with experiments. With the development of new theoretical and experimental tools and sample loading methods, the quest for metallic hydrogen accelerated recently delivering a wealth of new data, which are reviewed here. Published under license by AIP Publishing.

Gas has been detected in a number of debris disks. It is likely secondary, i.e., produced by colliding solids. Here, we report ALMA Band 8 observations of neutral carbon in the CO-rich debris disk around the 15-30 Myr old A-type star HD 32297. We find that C-0 is located in a ring at similar to 110 au with an FWHM of similar to 80 au and has a mass of (3.5 0.2) x 10(-3) M-circle plus. Naively, such a surprisingly small mass can be accumulated from CO photodissociation in a time as short as similar to 10(4) yr. We develop a simple model for gas production and destruction in this system, properly accounting for CO self-shielding and shielding by neutral carbon, and introducing a removal mechanism for carbon gas. We find that the most likely scenario to explain both C-0 and CO observations is one where the carbon gas is rapidly removed on a timescale of order a thousand years and the system maintains a very high CO production rate of similar to 15 M-circle plus Myr(-1), much higher than the rate of dust grind-down. We propose a possible scenario to meet these peculiar conditions: the capture of carbon onto dust grains, followed by rapid CO re-formation and rerelease. In steady state, CO would continuously be recycled, producing a CO-rich gas ring that shows no appreciable spreading over time. This picture might be extended to explain other gas-rich debris disks.