We use fast transient transmission and emission spectroscopies in the pulse laser heated diamond anvil cell to probe the energy-dependent optical properties of hydrogen at pressures of 10-150 GPa and temperatures up to 6000 K. Hydrogen is absorptive at visible to near-infrared wavelengths above a threshold temperature that decreases from 3000 K at 18 GPa to 1700 K at 110 GPa. Transmission spectra at 2400 K and 141 GPa indicate that the absorptive hydrogen is semiconducting or semimetallic in character, definitively ruling out a first-order insulator-metal transition in the studied pressure range.

We spectroscopically investigated the energy gap of the correlated antiferromagnetic insulator LaMnPO1-xFx (x = 0.0 and 0.04) as a function of temperature and pressure, separately, in conjunction with many-body electronic structure calculations. These results show that the electronic structure in all measured regimes is well described by a model that includes both Mott-Hubbard interactions and Hund's rule coupling. Moreover, we find that by applying external pressure, thereby reducing the effective Mott-Hubbard interaction and Hund's coupling, the energy gap in LaMnPO1 xFx can be fully closed, yielding a metallic state.

The detectability of planetesimal impacts on imaged exoplanets can be measured using Jupiter during the 1994 comet Shoemaker-Levy 9 events as a proxy. By integrating the whole planet flux with and without impact spots, the effect of the impacts at wavelengths from 2 to 4 is revealed. Jupiter's reflected light spectrum in the near-infrared is dominated by its methane opacity including a deep band at 2.3 mu m. After the impact, sunlight that would have normally been absorbed by the large amount of methane in Jupiter's atmosphere was instead reflected by the cometary material from the impacts. As a result, at 2.3 mu m, where the planet would normally have low reflectivity, it brightened substantially and stayed brighter for at least a month. (C) 2015 Elsevier Inc. All rights reserved.

The conduction of heat through minerals and melts at extreme pressures and temperatures is of central importance to the evolution and dynamics of planets. In the cooling Earth's core, the thermal conductivity of iron alloys defines the adiabatic heat flux and therefore the thermal and compositional energy available to support the production of Earth's magnetic field via dynamo action(1-3). Attempts to describe thermal transport in Earth's core have been problematic, with predictions of high thermal conductivity(4-7) at odds with traditional geophysical models and direct evidence for a primordial magnetic field in the rock record(8-10). Measurements of core heat transport are needed to resolve this difference. Here we present direct measurements of the thermal conductivity of solid iron at pressure and temperature conditions relevant to the cores of Mercury-sized to Earth-sized planets, using a dynamically laser-heated diamond-anvil cell(11,12). Our measurements place the thermal conductivity of Earth's core near the low end of previous estimates, at 18-44 watts per metre per kelvin. The result is in agreement with palaeomagnetic measurements(10) indicating that Earth's geodynamo has persisted since the beginning of Earth's history, and allows for a solid inner core as old as the dynamo.

Exoplanet detections have revolutionized astronomy, offering new insights into solar system architecture and planet demographics. While nearly 1,900 exoplanets have now been discovered and confirmed(1), none are still in the process of formation. Transition disks, protoplanetary disks with inner clearings(2-4) best explained by the influence of accreting planets(5), are natural laboratories for the study of planet formation. Some transition disks show evidence for the presence of young planets in the form of disk asymmetries(6,7) or infrared sources detected within their clearings, as in the case of LkCa 15 (refs 8, 9). Attempts to observe directly signatures of accretion onto protoplanets have hitherto proven unsuccessful(10). Here we report adaptive optics observations of LkCa 15 that probe within the disk clearing. With accurate source positions over multiple epochs spanning 2009-2015, we infer the presence of multiple companions on Keplerian orbits. We directly detect Ha emission from the innermost companion, LkCa 15 b, evincing hot (about 10,000 kelvin) gas falling deep into the potential well of an accreting protoplanet.

The only known compound of sodium and hydrogen is archetypal ionic NaH. Application of high pressure is known to promote states with higher atomic coordination, but extensive searches for polyhydrides with unusual stoichiometry have had only limited success in spite of several theoretical predictions. Here we report the first observation of the formation of polyhydrides of Na (NaH3 and NaH7) above 40GPa and 2,000 K. We combine synchrotron X-ray diffraction and Raman spectroscopy in a laser-heated diamond anvil cell and theoretical random structure searching, which both agree on the stable structures and compositions. Our results support the formation of multicenter bonding in a material with unusual stoichiometry. These results are applicable to the design of new energetic solids and high-temperature superconductors based on hydrogen-rich materials.

We report the discovery of a scattering component around the HD 141569 A circumstellar debris system, interior to the previously known inner ring. The discovered inner disk component, obtained in broadband optical light with Hubble Space Telescope/Space Telescope Imaging Spectrograph coronagraphy, was imaged with an inner working angle of 0 25, and can be traced from 0 ''.4 (similar to 46 AU) to 1 ''.0 (similar to 116 AU) after deprojection using i = 55 degrees. The inner disk component is seen to forward scatter in a manner similar to the previously known rings, has a pericenter offset of similar to 6 AU, and break points where the slope of the surface brightness changes. It also has a spiral arm trailing in the same sense as other spiral arms and arcs seen at larger stellocentric distances. The inner disk spatially overlaps with the previously reported warm gas disk seen in thermal emission. We detect no point sources within 2 ''(similar to 232 AU), in particular in the gap between the inner disk component and the inner ring. Our upper limit of 9 +/- 3 M-J is augmented by a new dynamical limit on single planetary mass bodies in the gap between the inner disk component and the inner ring of 1 M-J, which is broadly consistent with previous estimates.

The search of compounds with CxNy composition holds great promise for creating materials which would rival diamond in hardness due to the very strong covalent C-N bond. Early theoretical and experimental works on CxNy compounds were based on the hypothetical structural similarity of predicted C3N4 phases with known binary A(3)B(4) structural types; however, the synthesis of C3N4 other than g-C3N4 remains elusive. Here, we explore an elemental synthesis at high pressures and temperatures in which the compositional limitations due to the use of precursors in the early works are substantially lifted. Using in situ synchrotron X-ray diffraction and Raman spectroscopy, we demonstrate the synthesis of a highly incompressible Pnnm CN compound (x = y = 1) with sp(3)-hybridized carbon above 55 GPa and 7000 K. This result is supported by first-principles evolutionary search, which finds that CN is the most stable compound above 14 GPa. On pressure release below 6 GPa, the synthesized CN compound amorphizes, maintaining its 1:1 stoichiometry as confirmed by energy-dispersive X-ray spectroscopy. This work underscores the importance of understanding the novel high-pressure chemistry laws that promote extended 3D C-N structures, never observed at ambient conditions. Moreover, it opens a new route for synthesis of superhard materials based on novel stoichiometries

Transition disks (TDs) are intermediate stage circumstellar disks characterized by an inner gap within the disk structure. To test whether these gaps may have been formed by closely orbiting, previously undetected stellar companions, we collected high-resolution optical spectra of 31 TD objects to search for spectroscopic binaries (SBs). Twenty-four of these objects are in Ophiuchus and seven are within the Coronet, Corona Australis, and Chameleon I star-forming regions. We measured radial velocities for multiple epochs, obtaining a median precision of 400 ms(-1). We identified double-lined SB SSTc2d J163154.7-250324 in Ophiuchus, which we determined to be composed of a K7(+/- 0.5) and a K9(+/- 0.5) star, with orbital limits of a < 0.6 au and P < 150 days. This results in an SB fraction of 0.04(-0.03+)(0.12) in Ophiuchus, which is consistent with other spectroscopic surveys of non-TD objects in the region. This similarity suggests that TDs are not preferentially sculpted by the presence of close binaries and that planet formation around close binaries may take place over similar timescales to that around single stars.

Synthesis of high nitrogen containing materials has been the subject of research interest for use as alternative clean sources of fuel and explosives. Here we present experimental evidence for the photochemical synthesis of new energetic materials from sodium azide (NaN3) at 4.88.1 GPa. We show that excitation into the conduction band generates color centers within the compressed alpha-NaN3 phase lattice with minimal or no molecular N-2 evolution. Photochemical changes to the sample were monitored by X-ray diffraction (XRD), infrared (IR) absorption, and Raman spectroscopy. These high pressure products were found to be stable upon decompression at 300 K down to 1.6 GPa, although it is suspected that the material can be recoverable to ambient pressure with cold decompression.