Capture of highly volatile radioactive iodine is a promising application of metal-organic frameworks (MOFs), thanks to their high porosity with flexible chemical architecture. Specifically, strong charge-transfer binding of iodine to the framework enables efficient and selective iodine uptake as well as its long-term storage. As such, precise knowledge of the electronic structure of iodine is essential for a detailed modeling of the iodine sorption process, which will allow for rational design of iodophilic MOFs in the future. Here we probe the electronic structure of iodine in MOFs at variable iodine...framework interaction by Raman and optical absorption spectroscopy at high pressure (P). The electronic structure of iodine in the straight channels of SBMOF-1 (Ca-sdb, sdb = 4,4 ' sulfonyldibenzoate) is modified irreversibly at P > 3.4 GPa by charge transfer, marking a polymerization of iodine molecules into a 1D polyiodide chain. In contrast, iodine in the sinusoidal channels of SBMOF-3 (Cd-sdb) retains its molecular (I-2 ) character up to at least 8.4 GPa. Such divergent high-pressure behavior of iodine in the MOFs with similar port size and chemistry illustrates adaptations of the electronic structure of iodine to channel topology and strength of the iodine...framework interaction, which can be used to tailor iodine-immobilizing MOFs.

The Hunt for Observable Signatures of Terrestrial Systems survey searches for dust near the habitable zones (HZs) around nearby, bright main-sequence stars. We use nulling interferometry in the N band to suppress the bright stellar light and to probe for low levels of HZ dust around the 30 stars observed so far. Our overall detection rate is 18%, including four new detections, among which are the first three around Sun-like stars and the first two around stars without any previously known circumstellar dust. The inferred occurrence rates are comparable for early-type and Sun-like stars, but decrease from 60(-21)(+16)% for stars with previously detected cold dust to 8(-3)(+10)% for stars without such excess, confirming earlier results at higher sensitivity. For completed observations on individual stars, our sensitivity is five to ten times better than previous results. Assuming a lognormal excess luminosity function, we put upper limits on the median HZ dust level of 13 zodis (95% confidence) for a sample of stars without cold dust and of 26 zodis when focusing on Sun-like stars without cold dust. However, our data suggest that a more complex luminosity function may be more appropriate. For stars without detectable Large Binocular Telescope Interferometer (LBTI) excess, our upper limits are almost reduced by a factor of two, demonstrating the strength of LBTI target vetting for future exo-Earth imaging missions. Our statistics are limited so far, and extending the survey is critical to informing the design of future exo-Earth imaging surveys.

Half-Heusler compounds have recently been identified as promising thermoelectric materials, but their relatively high thermal conductivities impede the further improvement of thermoelectric performance. The knowledge of phonon vibrational properties provides a fundamental understanding of the thermal transport behavior of solids and thus could serve as a guidance on further suppressing the thermal conductivity. Herein, a highly efficient p-type half-Heusler thermoelectric alloy FeNb0.8Ti0.2Sb is taken as an example to explore its phonon vibrational properties. Phonon spectrum with the frequencies down to 10 cm(-1) and its evolution with pressure for the studied material are provided by Raman scattering. It is found that two vibrational modes with the frequency > 200 cm(-1) display a common mode frequency increase with increasing pressure. Based on the bulk modulus from synchrotron X-ray powder diffraction and phonon frequency shifts, the mode Gruneisen parameters are obtained. Our results establish characteristic phonon vibrational properties of this high-performance half-Heusler thermoelectric alloy. Published by AIP Publishing.

MagAO-X is an entirely new extreme adaptive optics system for the Magellan Clay 6.5 m telescope, funded by the NSF MRI program starting in Sep 2016. The key science goal of MagAO-X is high-contrast imaging of accreting protoplanets at H alpha. With 2040 actuators operating at up to 3630 Hz, MagAO-X will deliver high Strehls (> 70%), high resolution (19 mas), and high contrast (< 1 x 10(-4)) at H alpha (656 nm). We present an overview of the MagAO-X system, review the system design, and discuss the current project status.

Layered molybdenum dichalchogenides differ from the classic example of bilayer graphene with their unique electronic properties: the application of pressure can continuously tune electronic structure since the band gap is controlled by delicate interlayer interaction. Here, we have performed measurements of Raman scattering, synchrotron x-ray diffraction, electrical conductivity, and Hall coefficient combined with density functional theory calculations to synthetically study the pressure effect on 2H-MoTe2. Both the experiments and calculations consistently demonstrate that MoTe2 undergoes a semiconductor-to-metallic (S-M) transition above 10 GPa. Unlike MoS2, the S-M transition is driven by the gradual tunability of electric structure and band gap without structural transition. The applied pressure also effectively enhances conductivity and carrier concentration while reducing the mobility, which makes MoTe2 more suitable for applications than most other transition-metal dichalchogenides and allows it to be applied in strain-modulated optoelectronic devices.

The Immersion GRating INfrared Spectrometer (IGRINS) was designed for high-throughput with the expectation of being a visitor instrument at progressively larger observing facilities. IGRINS achieves R similar to 45000 and > 20,000 resolution elements spanning the H and K bands (1.45-2.5 mu m) by employing a silicon immersion grating as the primary disperser and volume-phase holographic gratings as cross-dispersers. After commissioning on the 2.7 meter Harlan J. Smith Telescope at McDonald Observatory, the instrument had more than 350 scheduled nights in the first two years. With a fixed format echellogram and no cryogenic mechanisms, spectra produced by IGRINS at different facilities have nearly identical formats. The first host facility for IGRINS was Lowell Observatory's 4.3-meter Discovery Channel Telescope (DCT). For the DCT a three-element fore-optic assembly was designed to be mounted in front of the cryostat window and convert the f/6.1 telescope beam to the f/8.8 beam required by the default IGRINS input optics. The larger collecting area and more reliable pointing and tracking of the DCT improved the faint limit of IGRINS, relative to the McDonald 2.7-meter, by similar to 1 magnitude. The Gemini South 8.1-meter telescope was the second facility for IGRINS to visit. The focal ratio for Gemini is f/16, which required a swap of the four-element input optics assembly inside the IGRINS cryostat. At Gemini, observers have access to many southern-sky targets and an additional gain of similar to 1.5 magnitudes compared to IGRINS at the DCT. Additional adjustments to IGRINS include instrument mounts for each facility, a glycol cooled electronics rack, and software modifications. Here we present instrument modifications, report on the success and challenges of being a visitor instrument, and highlight the science output of the instrument after four years and 699 nights on sky. The successful design and adaptation of IGRINS for various facilities make it a reliable forerunner for GMTNIRS, which we now anticipate commissioning on one of the 6.5 meter Magellan telescopes prior to the completion of the Giant Magellan Telescope.

Diatomic nitrogen is an archetypal molecular system known for its exceptional stability and complex behavior at high pressures and temperatures, including rich solid polymorphism, formation of energetic states, and an insulator-to-metal transformation coupled to a change in chemical bonding. However, the thermobaric conditions of the fluid molecular-polymer phase boundary and associated metallization have not been experimentally established. Here, by applying dynamic laser heating of compressed nitrogen and using fast optical spectroscopy to study electronic properties, we observe a transformation from insulating (molecular) to conducting dense fluid nitrogen at temperatures that decrease with pressure and establish that metallization, and presumably fluid polymerization, occurs above 125 GPa at 2500 K. Our observations create a better understanding of the interplay between molecular dissociation, melting, and metallization revealing features that are common in simple molecular systems.

Common particle characteristics needed for many applications may include size, eccentricity, porosity and refractive index. Determining such characteristics from scattered light is a primary goal of remote sensing. For other applications, like differentiating a hazardous particle from the natural background, information about higher fidelity particle characteristics may be required, including specific shape or chemical composition. While a complete characterization of a particle system from its scattered light through the inversion process remains unachievable, great strides have been made in providing information in the form of constraints on particle characteristics. Recent advances have been made in quantifying the characteristics of polydispersions of irregularly shaped particles by making comparisons of the light-scattering signals from model simulant particles. We show that when the refractive index is changed, the light-scattering characteristics from polydispersions of such particles behave monotonically over relatively large parameter ranges compared with those of monodisperse distributions of particles having regular shapes, like spheres, spheroids, etc. This allows for their properties to be interpolated, which results in a significant reduction of the computational load when performing inversions. Published by Elsevier Ltd.

In their comment, Desjarlais et al. claim that a small temperature drop occurs after isentropic compression of fluid deuterium through the first-order insulator-metal transition. We show that their calculations do not correspond to the experimental thermodynamic path, and that thermodynamic integrations with parameters from first-principles calculations produce results in agreement with our original estimate of the temperature drop.

Despite promising astrometric signals, to date there has been no success in direct imaging of a hypothesized third member of the Sirius system. Using the Clio instrument and MagAO adaptive optics system on the Magellan Clay 6.5 m telescope, we have obtained extensive imagery of Sirius through a vector apodizing phase plate (vAPP) coronagraph in a narrowband filter at 3.9 microns. The vAPP coronagraph and MagAO allow us to be sensitive to planets much less massive than the limits set by previous non-detections. However, analysis of these data presents challenges due to the target's brightness and unique characteristics of the instrument. We present a comparison of dimensionality reduction techniques to construct background illumination maps for the whole detector using the areas of the detector that are not dominated by starlight. Additionally, we describe a procedure for sub-pixel alignment of vAPP data using a physical-optics-based model of the coronagraphic PSF.