Synthesis of high nitrogen containing materials has been the subject of research interest for use as alternative clean sources of fuel and explosives. Here we present experimental evidence for the photochemical synthesis of new energetic materials from sodium azide (NaN3) at 4.88.1 GPa. We show that excitation into the conduction band generates color centers within the compressed alpha-NaN3 phase lattice with minimal or no molecular N-2 evolution. Photochemical changes to the sample were monitored by X-ray diffraction (XRD), infrared (IR) absorption, and Raman spectroscopy. These high pressure products were found to be stable upon decompression at 300 K down to 1.6 GPa, although it is suspected that the material can be recoverable to ambient pressure with cold decompression.

The ability of Earth's mantle to conduct heat by radiation is determined by optical properties of mantle phases. Optical properties of mantle minerals at high pressure are accessible through diamond anvil cell experiments, but because of the intense thermal radiation at T > 1000 K such studies are limited to lower temperatures. Accordingly, radiative thermal conductivity at mantle conditions has been evaluated with the assumption of the temperature-independent optical properties. Particularly uncertain is the temperature-dependence of optical properties of lower mantle minerals across the spin transition, as the spin state itself is a strong function of temperature. Here we use laser-heated diamond anvil cells combined with a pulsed ultra-bright supercontinuum laser probe and a synchronized time-gated detector to examine optical properties of high and low spin ferrous iron at 45-73 GPa up to 1600 K in an octahedral crystallographic unit (FeO6), one of the most abundant building blocks in the mantle. Siderite (FeCO3) is used as a model for FeO6-octahedra as it contains no ferric iron and exhibits a sharp optically apparent pressure-induced spin transition at 44 GPa, simplifying data interpretation. We find that the optical absorbance of low spin FeO6 increases with temperature due to the partially lifted Laporte selection rule. The temperature-induced low-to-high spin transition, however, results in a dramatic drop in absorbance of the FeO6 unit in siderite. The absorption edge (Fe-O charge transfer) red-shifts (similar to 1 cm(-1)/K) with increasing temperature and at T > 1600 K and P > 70 GPa becomes the dominant absorption mechanism in the visible range, suggesting its superior role in reducing the ability of mantle minerals to conduct heat by radiation. This implies that the radiative thermal conductivity of analogous FeO6-bearing minerals such as ferropericlase, the second most abundant mineral in the Earth's lower mantle, is substantially reduced approaching the core-mantle boundary conditions. (C) 2016 Elsevier B.V. All rights reserved.

The Large Binocular Telescope Interferometer (LBTI) is a versatile instrument designed for high angular resolution and high-contrast infrared imaging (1.5-13 mu m). In this paper, we focus on the mid-infrared (8-13 mu m) nulling mode and present its theory of operation, data reduction, and on-sky performance as of the end of the commissioning phase in 2015 March. With an interferometric baseline of 14.4 m, the LBTI nuller is specifically tuned to resolve the habitable zone of nearby main-sequence stars, where warm exozodiacal dust emission peaks. Measuring the exozodi luminosity function of nearby main-sequence stars is a key milestone to prepare for future exo-Earth direct imaging instruments. Thanks to recent progress in wavefront control and phase stabilization, as well as in data reduction techniques, the LBTI demonstrated in 2015 February a calibrated null accuracy of 0.05% over a 3 hr long observing sequence on the bright nearby A3V star beta Leo. This is equivalent to an exozodiacal disk density of 15-30. zodi for a Sun-like star located at 10 pc, depending on the adopted disk model. This result sets a new record for high-contrast mid-infrared interferometric imaging and opens a new window on the study of planetary systems.

Synchrotron x-ray diffraction and Raman spectroscopy have been used to study the chemical reactions of molecular hydrogen (H-2) with sulfur (S) at high pressures. We find theoretically predicted Cccm and Im (3) over barm H3S to be the reaction products at 50 and 140 GPa, respectively. Im (3) over barm H3S is a stable crystalline phase above 140 GPa and it transforms to R3mH(3)S on pressure release below 140 GPa. The latter phase is (meta) stable down to at least 70 GPa where it transforms to Cccm H3S upon annealing (T < 1300 K) to overcome the kinetic hindrance. Cccm H3S has an extended structure with symmetric hydrogen bonds at 50 GPa, and upon decompression it experiences a transformation to a molecular mixed H2S-H-2 structure below 40 GPa without any apparent change in the crystal symmetry.

The elasticity at high pressure of solid hydrogen in hexagonal close-packed (hcp) phase I has been examined experimentally by laser acoustics technique in a diamond anvil cell, up to 55 GPa at 296 K, and theoretically using pair and three-body semiempirical potentials, up to 160 GPa. In the experiments on H-2 and D-2, the compressional sound velocity has been measured; the Poisson's ratio has been determined by combining these data with the previously reported equation of state. At room temperature, the difference between the adiabatic and isothermal processes vanishes above 25 GPa but cannot be neglected at lower pressure. Theoretically, all five elastic constants of hcp hydrogen have been calculated, and various derived elastic quantities are presented. The elastic anisotropy of hcp hydrogen was found to be significant, with Delta P approximate to 1.2, Delta S-1 Delta approximate to 1.7, and Delta S-2 approximate to 1. Calculations suggest the Poisson's ratio to decrease with pressure reaching a minimum value of 0.28 at 145 GPa. In the experiment, the Poisson's ratio is also found to decrease with pressure. Theoretical calculations show that the inclusion of zero-point vibrations on the elastic properties of H-2 does not result in any drastic changes of the behavior of the elastic quantities.

Young giant exoplanets are a unique laboratory for understanding cool, low-gravity atmospheres. A quintessential example is the massive extrasolar planet beta Pic b, which is 9 AU from and embedded in the debris disk of the young nearby A6V star beta Pictoris. We observed the system with first light of the Magellan Adaptive Optics (MagAO) system. In Paper I we presented the first CCD detection of this planet with MagAO VisAO. Here we present four MagAO+Clio images of beta Pic b at 3.1 pm, 3.3 pm,, and M', including the first observation in the fundamental CH4 band. To remove systematic errors from the spectral energy distribution (SED), we re-calibrate the literature photometry and combine it with our own data, for a total of 22 independent measurements at 16 passbands from 0.99 to 4.8 mu m. Atmosphere models demonstrate the planet is cloudy but are degenerate in effective temperature and radius. The measured SED now covers >80% of the planet's energy, so we approach the bolometric luminosity empirically. We calculate the luminosity by extending the measured SED with a blackbody and integrating to find log(40i/L0) = 3.78 0.03. From our bolometric luminosity and an age of 23 +/- 3 Myr, hot-start evolutionary tracks give a mass of 12.7 +/- 0.3 M-Jup, radius of 1.45 +/- 0.02 R-Jup, and T-eff of 1708 +/- 23 K (model-dependent errors not included). Our empirically determined luminosity is in agreement with values from atmospheric models (typically -3.8 dex), but brighter than values from the field-dwarf bolometric correction (typically -3.9 dex), illustrating the limitations in comparing young exoplanets to old brown dwarfs.

A combined theoretical and experimental study of lithium palladium deuteride (Li2PdD2) subjected to pressures up to 50 GPa reveals one structural phase transition near 10 GPa, detected by synchrotron powder x-ray diffraction, and metadynamics simulations. The ambient-pressure tetragonal phase of Li2PdD2 transforms into a monoclinic C2/m phase that is distinct from all known structures of alkali metal-transition metal hydrides/deuterides. The structure of the high-pressure phase was characterized using ab initio computational techniques and from refinement of the powder x-ray diffraction data. In the high-pressure phase, the PdD2 complexes lose molecular integrity and are fused to extended [PdD2](infinity) chains. The discovered phase transition and new structure are relevant to the possible hydrogen storage application of Li2PdD2 and alkali metal-transition metal hydrides in general. Published by AIP Publishing.

We present a kinematic analysis of 152 low surface gravity M7-L8 dwarfs by adding 18 new parallaxes (including 10 for comparative field objects), 38 new radial velocities, and 19 new proper motions. We also add low-or moderate-resolution near-infrared spectra for 43 sources confirming their low surface gravity features. Among the full sample, we find 39 objects to be high-likelihood or new bona fide members of nearby moving groups, 92 objects to be ambiguous members and 21 objects that are non-members. Using this age-calibrated sample, we investigate trends in gravity classification, photometric color, absolute magnitude, color-magnitude, luminosity, and effective temperature. We find that gravity classification and photometric color clearly separate 5-130Myr sources from >3Gyr field objects, but they do not correlate one to one with the narrower 5-130Myr age range. Sources with the same spectral subtype in the same group have systematically redder colors, but they are distributed between 1 and 4s from the field sequences and the most extreme outlier switches between intermediate-and low-gravity sources either confirmed in a group or not. The absolute magnitudes of low-gravity sources from the J band through W3 show a flux redistribution when compared to equivalently typed field brown dwarfs that is correlated with spectral subtype. Low-gravity, late-type L dwarfs are fainter at J than the field sequence but brighter by W3. Low-gravity M dwarfs are >1 mag brighter than field dwarfs in all bands from J through W3. Clouds, which are a far more dominant opacity source for L dwarfs, are the likely cause. On color-magnitude diagrams, the latest-type, low-gravity L dwarfs drive the elbow of the L/T transition up to 1mag redder and 1mag fainter than field dwarfs at M-J but are consistent with or brighter than the elbow at M-W1 and M-W2. We conclude that low-gravity dwarfs carry an extreme version of the cloud conditions of field objects to lower temperatures, which logically extends into the lowest-mass, directly imaged exoplanets. Furthermore, there is an indication on color-magnitude diagrams (CMDs; such as M-J versus (J-W2)) of increasingly redder sequences separated by gravity classification, although it is not consistent across all CMD combinations. Examining bolometric luminosities for planets and low-gravity objects, we confirm that (in general) young M dwarfs are overluminous while young L dwarfs are normal compared to the field. Using model extracted radii, this translates into normal to slightly warmer M dwarf temperatures compared to the field sequence and lower temperatures for L dwarfs with no obvious correlation with the assigned moving group.

Helium is generally understood to be chemically inert and this is due to its extremely stable closed-shell electronic configuration, zero electron affinity and an unsurpassed ionization potential. It is not known to form thermodynamically stable compounds, except a few inclusion compounds. Here, using the ab initio evolutionary algorithm USPEX and subsequent high-pressure synthesis in a diamond anvil cell, we report the discovery of a thermodynamically stable compound of helium and sodium, Na2He, which has a fluorite-type structure and is stable at pressures >113 GPa. We show that the presence of He atoms causes strong electron localization and makes this material insulating. This phase is an electride, with electron pairs localized in interstices, forming eight-centre two-electron bonds within empty Na-8 cubes. We also predict the existence of Na2HeO with a similar structure at pressures above 15 GPa.

HD 11112 is an old, Sun-like star that has a long-term radial velocity (RV) trend indicative of a massive companion on a wide orbit. Here we present direct images of the source responsible for the trend using the Magellan Adaptive Optics system. We detect the object (HD 11112B) at a separation of 2 2 (100 au) at multiple wavelengths spanning 0.6-4 mu m. and show that it is most likely a gravitationally bound cool white dwarf. Modeling its spectral energy distribution suggests that its mass is 0.9-1.1M(circle dot), which corresponds to very high eccentricity, near edge-on orbits from a. Markov chain Monte Carlo analysis of the RV and imaging data together. The total age of the white dwarf is > 2 sigma, which is discrepant with that of the primary star under most assumptions. The problem can be resolved if the white dwarf progenitor was initially a double white dwarf binary that then merged into the observed high-mass white dwarf. HD 11112B is a unique and intriguing benchmark object that can be used to calibrate atmospheric and evolutionary models of cool white dwarfs and should thus continue to be monitored by RV and direct imaging over the coming years.