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Abstract
The use of magnetic susceptibility (& chi;) as a means of assessing heavy metal pollution in soils has been explored by researchers, yielding varying results in terms of the correlations between & chi; with heavy metals. The efficacy of & chi; as an indicator of soil heavy metal pollution remains a topic of debate. This study aims to elucidate the interrelationships between & chi;, iron oxides, and heavy metals in soil through the application of a modified 5-step sequential extraction procedure (SEP), and to identify an effective approach for assessing metal concentrations in soil using magnetic susceptibility measurements. The soil samples were collected from a typical alluvial island in the lower Yangtze River, China, and a total of 6 forms (exchangeable and acid soluble fraction, easily reducible fraction, oxidizable fraction, amorphous iron oxide, crystallized iron oxyhydroxides and residual fraction) were partitioned and their heavy metal concentrations and & chi; were analyzed. The results show that crystalline Fe oxyhydroxides and residual fractions are the two uppermost fractions of heavy metals. By combining the fractionation of elements with the variation of & chi; of the soil during the processing of SEP, it was inferred that the external input of Fe, Pb, Cr and Cd in the soil likely originated from the vicinal steel production. The correlation analysis revealed a significant correlation between heavy metal concentrations and & chi; in the residual fraction, whereas no significant correlations were observed between the concentrations of heavy metals and & chi; in the bulk soil samples. It is recommended that the evaluation of heavy metal contamination in the soil neighboring industrial sites can be conducted via magnetic susceptibility measurements subsequent to the elimination of crystalline iron oxyhydroxides.
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Missing Headshot

Jack Lonergan

Ph.D. Student

Yu Zhao headshot

Yu Zhao

Ph.D. Student

Missing Headshot

Siddhesh Raut

Ph.D. Student

Missing Headshot

Meghan O'Brien

Ph.D. Student

Annastasia Haynie

Annastasia Haynie

CTAC Ph.D. Student

Abstract
In maize (Zea mays), fungal-elicited immune responses include the accumulation of terpene synthase (TPS) and cytochrome P450 monooxygenases (CYP) enzymes resulting in complex antibiotic arrays of sesquiterpenoids and diterpenoids, including alpha/beta-selinene derivatives, zealexins, kauralexins and dolabralexins. To uncover additional antibiotic families, we conducted metabolic profiling of elicited stem tissues in mapping populations, which included B73 x M162W recombinant inbred lines and the Goodman diversity panel. Five candidate sesquiterpenoids associated with a chromosome 1 locus spanning the location of ZmTPS27 and ZmTPS8. Heterologous enzyme co-expression studies of ZmTPS27 in Nicotiana benthamiana resulted in geraniol production while ZmTPS8 yielded alpha-copaene, delta-cadinene and sesquiterpene alcohols consistent with epi-cubebol, cubebol, copan-3-ol and copaborneol matching the association mapping efforts. ZmTPS8 is an established multiproduct alpha-copaene synthase; however, ZmTPS8-derived sesquiterpene alcohols are rarely encountered in maize tissues. A genome wide association study further linked an unknown sesquiterpene acid to ZmTPS8 and combined ZmTPS8-ZmCYP71Z19 heterologous enzyme co-expression studies yielded the same product. To consider defensive roles for ZmTPS8, in vitro bioassays with cubebol demonstrated significant antifungal activity against both Fusarium graminearum and Aspergillus parasiticus. As a genetically variable biochemical trait, ZmTPS8 contributes to the cocktail of terpenoid antibiotics present following complex interactions between wounding and fungal elicitation.
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Chris Carchedi

Christopher Carchedi

Carnegie Postdoctoral Fellow

Abstract
The Transiting Exoplanet Survey Satellite (TESS) will search for planets transiting bright and nearby stars. TESS has been selected by NASA for launch in 2017 as an Astrophysics Explorer mission. The spacecraft will be placed into a highly elliptical 13.7-day orbit around the Earth. During its 2-year mission, TESS will employ four wide-field optical charge-coupled device cameras to monitor at least 200,000 main-sequence dwarf stars with I-C approximate to 4-13 for temporary drops in brightness caused by planetary transits. Each star will be observed for an interval ranging from 1 month to 1 year, depending mainly on the star's ecliptic latitude. The longest observing intervals will be for stars near the ecliptic poles, which are the optimal locations for follow-up observations with the James Webb Space Telescope. Brightness measurements of preselected target stars will be recorded every 2 min, and full frame images will be recorded every 30 min. TESS stars will be 10 to 100 times brighter than those surveyed by the pioneering Kepler mission. This will make TESS planets easier to characterize with follow-up observations. TESS is expected to find more than a thousand planets smaller than Neptune, including dozens that are comparable in size to the Earth. Public data releases will occur every 4 months, inviting immediate community-wide efforts to study the new planets. The TESS legacy will be a catalog of the nearest and brightest stars hosting transiting planets, which will endure as highly favorable targets for detailed investigations. (C) The Authors. Published by SPIE under a Creative Commons Attribution 3.0 Unported License. Distribution or reproduction of this work in whole or in part requires full attribution of the original publication, including its DOI.
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Abstract
We report the detection of a transiting planet around it Men (HD 39091), using data from the Transiting Exoplanet Survey Satellite (TESS). The solar-type host star is unusually bright (V= 5.7) and was already known to host a Jovian planet on a highly eccentric, 5.7 yr orbit. The newly discovered planet has a size of 2.04 +/- 0.05 R-circle plus and an orbital period of 6.27 days. Radial-velocity data from the High-Accuracy Radial-velocity Planet Searcher and Anglo-Australian Telescope/University College London Echelle Spectrograph archives also displays a 6.27 day periodicity, confirming the existence of the planet and leading to a mass determination of 4.82 +/- 0.85 M-circle plus. The star's proximity and brightness will facilitate further investigations, such as atmospheric spectroscopy, asteroseismology, the Rossiter-McLaughlin effect, astrometry, and direct imaging.
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