Seeing pristine material from the donor star in a type Ia supernova (SN Ia) explosion can reveal the nature of the binary system. In this paper, we present photometric and spectroscopic observations of SN 2020esm, one of the best-studied SNe of the class of "super-Chandrasekhar" SNe Ia (SC SNe Ia), with data obtained 12 to +360 days relative to peak brightness, obtained from a variety of ground- and space-based telescopes. Initially misclassified as a type II supernova, SN 2020esm peaked at M-B = -19.9 mag, declined slowly (Delta m(15)(B) = 0.92 mag), and had particularly blue UV and optical colors at early times. Photometrically and spectroscopically, SN 2020esm evolved similarly to other SC SNe Ia, showing the usual low ejecta velocities, weak intermediate-mass elements, and the enhanced fading at late times, but its early spectra are unique. Our first few spectra (corresponding to a phase of greater than or similar to 10 days before peak) reveal a nearly pure carbon/oxygen atmosphere during the first days after explosion. This composition can only be produced by pristine material, relatively unaffected by nuclear burning. The lack of H and He may further indicate that SN 2020esm is the outcome of the merger of two carbon/oxygen white dwarfs. Modeling its bolometric light curve, we find an Ni-56 mass of 1.23(-0.14)(+0.14) M-circle dot and an ejecta mass of 1.75(-0.20)(+0.32)M(circle dot), in excess of the Chandrasekhar mass. Finally, we discuss possible progenitor systems and explosion mechanisms of SN 2020esm and, in general, the SC SNe Ia class.

We present Hubble Space Telescope (HST) observations of the Type IIb supernova (SN) SN 2016gkg at 652, 1698, and 1795 days from explosion with the Advanced Camera for Surveys (ACS) and Wide Field Camera 3 (WFC3). Comparing to pre-explosion imaging from 2001 obtained with the Wide Field Planetary Camera 2, we demonstrate that SN 2016gkg is now fainter than its candidate counterpart in the latest WFC3 imaging, implying that the counterpart has disappeared and confirming that it was the SN progenitor star. We show the latest light curve and Keck spectroscopy of SN 2016gkg, which imply that SN 2016gkg is declining more slowly than the expected rate for Co-56 decay during its nebular phase. We find that this emission is too luminous to be powered by other radioisotopes and infer that SN 2016gkg is entering a new phase in its evolution where it is powered primarily by interaction with circumstellar matter. Finally, we reanalyze the progenitor star spectral energy distribution and late-time limits in the context of binary evolution models. Including emission from a potential companion star, we find that all such predicted companion stars would be fainter than our limiting magnitudes.

The tidal interactions between a planet and moon can provide insight into the properties of the host planet. The recent exomoon candidates Kepler-1708 b-i and Kepler-1625 b-i are Neptune-sized satellites orbiting Jupiter-like planets and provide an opportunity to apply such methods. We show that if the tidal migration time is roughly equal to the age of these systems, then the tidal dissipation factor Q for the planets Kepler-1708 b and Kepler-1625 b have values of similar to 3 x 10(5)-3 x 10(6) and similar to 1.5 x 10(5)-4 x 10(5), respectively. In each case, these are consistent with estimates for gas-giant planets. Even though some work suggests an especially large semimajor axis for Kepler-1625 b-i, we find that this would imply a surprisingly low Q similar to 2000 for a gas giant unless the moon formed at essentially its current position. More detailed predictions for the moons' initial semimajor axis could provide even better constraints on Q, and we discuss the formation scenarios for a moon in this context. Similar arguments can be used as more exomoons are discovered in the future to constrain exoplanet interior properties. This could be especially useful for exoplanets near the sub-Neptune/super-Earth radius gap where the planet structure is uncertain.

1991T-like supernovae are the luminous, slow-declining extreme of the Branch shallow-silicon (SS) subclass of Type Ia supernovae. They are distinguished by extremely weak Ca ii H & K and Si ii lambda 6355 and strong Fe iii absorption features in their optical spectra at pre-maximum phases, and have long been suspected to be over-luminous compared to normal Type Ia supernovae. In this paper, the pseudo-equivalent width of the Si ii lambda 6355 absorption obtained at light curve phases from <= +10 days is combined with the morphology of the i-band light curve to identify a sample of 1991T-like supernovae in the Carnegie Supernova Project II. Hubble diagram residuals show that, at optical as well as near-infrared wavelengths, these events are over-luminous by similar to 0.1-0.5 mag with respect to the less extreme Branch SS (1999aa-like) and Branch core-normal supernovae with similar B-band light-curve decline rates.

Chiral aminomethylnaphthols have been prepared highly diastereoselective by means of three-component `Betti condensation", using steroidal 2-naphthol analogue, synthesized from estrone. The use of 2-methoxybenzaldehyde or 2-pyridinecarboxaldehyde as aldehyde component and (S)-(-)-1-phenylethan-1-amine or (S)-(-)-1-(naphthalen-2-yl)ethan-1-amine, as chiral non-racemic amine component providing the diastereoselectivity, allowed the synthesis of structurally diverse aminomethylnaphthols. The latter easily form 1,3-dihydronaphthoxazines through reaction with formaldehyde. The absolute configurations of the new aminomethylnaphthols synthesized have been determined through advanced nuclear magnetic resonance (NMR) experiments and confirmed by X-ray crystallography. The chiral steroidal aminomethylnaphthols obtained as pure diastereoisomers have been evaluated as pre-catalysts in the enantioselective addition of diethylzinc to aldehydes with enantioselectivities of up to 97% ee.

Tracing the deep geological water cycle requires knowledge of the hydrogen isotope systematics between and within hydrous materials. For quenched hydrous alkali-silicate melts, hydrogen NMR reveals a distinct heterogeneity in the distribution of stable hydrogen isotopes (D, H) within the silicate tetrahedral network, where deuterons concentrate strongly in network regions that are associated with alkali cations. Previous hydrogen NMR studies performed in the sodium tetrasilicate system (Na2O x 4SiO2, NS4) with a 1:1 D2O/H2O ratio showed on average 1300 %o deuterium enrichment in the alkali-associated network, but the effect on varying bulk D2O/ H2O ratios on this intramolecular isotope effect remained unconstrained. Experiments in the hydrous sodium tetrasilicate system with 8 wt% bulk water and varying bulk D2O/H2O ratios were performed at 1400 degrees C and 1.5 GPa. It is found that both hydrogen isotopes preferably partition into the silicate network that is associated with alkali ions. The partitioning is always stronger for the deuterated than for the protonated hydrous species. The relative enrichment of deuterium over protium in the alkali-associated network, i.e., the intramolecular isotope effect, correlates positively with the D2O/H2O bulk ratio of the hydrous NS4 system. Modeled for natural deuterium abundance (D/H near 1.56 x 10-4), a 1.4-fold (c. 340 %o) deuterium enrichment in the alkaliassociated silicate network is predicted. The partitioning model further predicts a positive correlation between the bulk water content of the silicate melt and the intramolecular deuterium partitioning into the alkaliassociated silicate network. Such heterogeneities may explain the magnitude and direction of hydrogen isotope fractionation in hydrous silicate melts coexisting with silicate-saturated fluids. As such, this intramolecular isotope effect appears to be an effective mechanism for deuterium separation, particularly in hydrous magmatic settings, such as subduction zones.

Physiological and gene expression studies of deep-sea bacteria under pressure conditions similar to those experienced in their natural habitat are critical for understanding growth kinetics and metabolic adaptations to in situ conditions. The Campylobacterium (aka Epsilonproteobacterium) Nautilia sp. strain PV-1 was isolated from hydrothermal fluids released from an active deep-sea hydrothermal vent at 9° N on the East Pacific Rise. Strain PV-1 is a piezophilic, moderately thermophilic, chemolithoautotrophic anaerobe that conserves energy by coupling the oxidation of hydrogen to the reduction of nitrate or elemental sulfur. Using a high-pressure-high temperature continuous culture system, we established that strain PV-1 has the shortest generation time of all known piezophilic bacteria and we investigated its protein expression pattern in response to different hydrostatic pressure regimes. Proteogenomic analyses of strain PV-1 grown at 20 and 5MPa showed that pressure adaptation is not restricted to stress response or homeoviscous adaptation but extends to enzymes involved in central metabolic pathways. Protein synthesis, motility, transport, and energy metabolism are all affected by pressure, although to different extents. In strain PV-1, low-pressure conditions induce the synthesis of phage-related proteins and an overexpression of enzymes involved in carbon fixation.