The atmospheres of gas giant planets are thought to be inhomogeneous due to weather and patchy clouds. We present two full nights of coronagraphic observations of the HR 8799 planets using the CHARIS integral field spectrograph behind the SCExAO adaptive optics system on the Subaru Telescope to search for spectrophomometric variability. We did not detect significant variability signals, but placed the lowest variability upper limits for HR 8799c and d. Based on injection-recovery tests, we expected to have a 50% chance to detect signals down to 10% H-band photometric variability for HR 8799c and down to 30% H-band variability for HR 8799d. We also investigated spectral variability and expected a 50% chance to recover 20% variability in the H/K flux ratio for HR 8799c. We combined all the data from the two nights to obtain some of the most precise spectra obtained for HR 8799c, d, and e. Using a grid of cloudy radiative-convective-thermochemical equilibrium models, we found all three planets prefer supersolar metallicity with effective temperatures of similar to 1100 K. However, our high signal-to-noise spectra show that HR 8799d has a distinct spectrum from HR 8799c, possibly preferring more vertically extended and uniform clouds and indicating that the planets are not identical.

As an element ubiquitous in the Solar system, the isotopic composition of iron exhibits rich variations in different planetary reservoirs. Such variations reflect the diverse range of differentiation and evolution processes experienced by their parent bodies. A key in deciphering iron isotope variations among planetary samples is to understand how iron isotopes fractionate during core formation. Here we report new Nuclear Resonant Inelastic X-ray Scattering experiments on silicate glasses of bulk silicate Earth compositions to measure their force constants at high pressures of up to 30 GPa. The force constant results are subsequently used to constrain iron isotope fractionation during core formation on terrestrial planets. Using a model that integrates temperature, pressure, core composition, and redox state of the silicate mantle, we show that core formation might lead to an isotopically light mantle for small planetary bodies but a heavy one for Earth-sized terrestrial planets.

Despite decades of work, the origin of pallasite meteorites has remained enigmatic. Long thought to be samples of the core-mantle boundary of differentiated asteroids, more recent studies have suggested a range of mechanisms for pallasite formation. These include olivine-metal mixing during a planetesimal collision and the intrusion of over-pressured core liquids into a planetesimal mantle. Establishing if the olivine and metal that comprise pallasites were once equilibrated at high temperature remains key to discriminating between these hypotheses. To this end, we determined the iron isotope compositions of olivine and metal in eleven main-group pallasites and found, in all cases, that olivine is isotopically lighter than metal. To interpret these data, we constrained the olivine-metal equilibrium Fe isotope fractionation with ab initio calculations and high temperature experiments. These independent approaches show that olivine preferentially incorporates the heavy isotopes of iron relative to metal. Our results demonstrate that pallasitic olivine and metal never achieved isotopic equilibrium with respect to iron. This precludes extended cooling at high temperature and is best reconciled with an impact origin for the main-group pallasites.