In order to apply the vanadium (V) stable isotope system for studies of planetary accretion and evolution in the solar system and redox variations in terrestrial magmatic processes, the V isotope composition of the Bulk Silicate Earth (BSE) needs to be precisely constrained. Previous studies have shown that fertile peridotites have systematically higher V-51/V-50 ratios than MORB. This, however, is in conflict with the theoretical prediction that mantle melting residues should be enriched in V-50 rather than V-51. To address these issues, a more precise estimate of the V isotope composition of the BSE is required. This study presents delta V-51 data for eleven peridotite xenoliths from two late Cenozoic eruption centers at Tariat in central Mongolia, ten komatiites from five localities ranging in age between 3.48 and 2.41 Ga, and four 1.98 Ga picrites from the Onega Plateau in Fennoscandia. The mean delta V-51 for fertile spinel lherzolites is -0.91 +/- 0.06 parts per thousand (2SD, n = 8). They show no resolvable difference in V isotope compositions compared to three moderately to highly refractory peridotite xenoliths analyzed, with a mean 5 51 V of -0.93 +/- 0.01 parts per thousand (2SD, n = 3). The mean delta V-51 for the komatiites is -0.91 +/- 0.05 parts per thousand (2SD, n = 10), which is identical to that for the fertile peridotites. Based on the V isotope compositions of the peridotites and komatiites analyzed in this study, the mean delta V-51 of the BSE is estimated to be -0.91 +/- 0.09 parts per thousand (2SD, n = 18).

The analysis of lunar samples returned to Earth by the Apollo and Luna missions changed our view of the processes involved in planet formation. The data obtained on lunar samples brought to light the importance during planet growth of highly energetic collisions that lead to global-scale melting. This violent birth determines the initial structure and long-term evolution of planets. Once past its formative era, the lunar surface has served as a recorder of more than 4 billion years of interaction with the space environment. The chronologic record of lunar cratering determined from the returned samples underpins age estimates for planetary surfaces throughout the inner Solar System and provides evidence of the dynamic nature of the Solar System during the planet-forming era.

Substantial quantities of sediments are known to enter the deep lithosphere at subduction zones, but the extent to which sediments melt and the process involved in sediment contribution to the deep lithosphere are inadequately understood. Vigorous debate continues about whether the subducted sediment component is terrigenous or pelagic and transported as a hydrous melt, an aqueous fluid, or bulk sediment. In this contribution, we conduct an integrated study on a variety of deep-seated xenoliths in the Neogene Hannuoba basalts from the northern margin of the North China Craton. Among these xenoliths, clinopyroxenite xenoliths are compositionally and isotopically distinct. Mineral chemistry shows that the clinopyroxenite xenoliths come from a depth near the MOHO, rather than from the mantle as suggested previously. The clinopyroxenite xenoliths have extremely evolved Sr-Nd-Hf isotopic compositions and are interpreted to have a late Archean protolith age. The extremely low contents of Cr and Ni for the clinopyroxenite xenoliths preclude a magmatic origin. Instead, a metasomatic origin is suggested, which is strongly supported for the clinopyroxenites by the occurrence of hydrous minerals and high contents of large-ion-lithophile elements (K, Rb, Ba, Th and Sr) and light rare earth elements, as well as elevated delta O-18 (9.9-11.3 parts per thousand) and light delta Mg-26 (-1.04 parts per thousand to 1.42 parts per thousand) isotopic compositions. Furthermore, their high high-field-strength element (Nb, Ta, Zr and Hf) contents indicate that the metasomatic agent is a hydrous melt, rather than an aqueous fluid. The metasomatic melts are considered to be derived from a mixed source of sedimentary carbonates and ancient, felsic continental materials. A combination of zircon ages and oxygen isotope data for the clinopyroxenite xenoliths further restricts the timing of metasomatism to the late Paleozoic. Considering the regional tectonic setting, the sediments most likely came from the subducted Paleo-Asian oceanic slab. Thus the Hannuoba clinopyroxenite xenoliths provide direct evidence for melting of the subducted Paleo-Asian oceanic slab sediment and its interaction with the deep lithosphere. The data show that melting of subducted sediments can take place at a much shallower depth than commonly thought and place an independent constraint on future models of slab geotherms. (C) 2019 Elsevier Ltd. All rights reserved.

To constrain the deformation, thermal evolution, and seismic properties of the mantle lithosphere beneath the Hangay Dome, we have analyzed the microstructures, crystal preferred orientations (CPO), and hydrogen concentrations of olivine and pyroxenes of 50 mantle xenoliths carried up by Cenozoic basalts from Zala, Haer, and Shavaryn-Tsaram from Tariat, Mongolia. Most xenoliths are medium- to coarse-grained spinel-lherzolites, but four contain garnet + spinel. Coarse granular, highly annealed microstructures predominate. The microstructures are associated with well-developed CPO, typical of deformation under high temperature, moderate pressure, and dry conditions. The hydrogen concentrations in olivine, orthopyroxene, and clinopyroxene are low and range around 5, 75, and 147 ppm H2O wt, respectively. Together, microstructures and CPO indicate that ductile deformation was followed by static recrystallization, which has annealed the microstructures but preserved the CPO and, hence, the anisotropy of physical properties. Lack of correlation between annealing and equilibrium temperatures suggest that the annealing is due to a long quiescence episode since the last deformation episode. Here, there is not evidence that the formation of Hangay Dome is associated with recent deformation in the lithospheric mantle. Calculated seismic properties show moderate seismic anisotropy, with fast propagation of P waves and polarization of S waves parallel to the flow direction and low birefringence for S waves propagating obliquely to the flow plane. The results are consistent with weak P wave anomalies but not with the strong low S wave velocity anomalies predicted by some tomographic models or with the high conductivity inferred from magnetotelluric data for the lithospheric mantle beneath the Hangay Dome.

The Mn-53-Cr-53 short-lived radionuclide decay system is a powerful tool to investigate the timescales of early solar system processes. A complication arises, however, from the fact that spallation and thermal/epithermal neutron capture processes induced by cosmic rays can significantly alter Cr-53/Cr-52 ratios in solar system objects that have long exposure ages and high Fe/Cr ratios. Quantifying these cosmogenic effects helps constrain the cosmic ray exposure history of extraterrestrial samples. The isotopic shifts produced by cosmic ray irradiation also need to be corrected before the Cr isotope systematics can be used as a dating tool and as a tracer of nucleosynthetic provenance. To investigate the impact of cosmogenic production on Cr, the Cr isotopic compositions of 25 samples from 16 iron meteorites belonging to nine different chemical groups were measured. The measurements show that exposure to cosmic rays can cause large coupled excesses in epsilon Cr-53 (up to +268.29 +/- 0.14; 2SE) and epsilon Cr-54 (up to +1053.78 +/- 0.72; 2SE) with a best fit line of epsilon Cr-54 = (3.90 +/- 0.03) x epsilon Cr-53. The magnitude of Cr isotope production is controlled by various factors including the exposure age, the chemical composition (i.e., Cr concentration and Ni/Fe ratio) and shielding conditions. Nevertheless, the correlation of epsilon Cr-53 and epsilon Cr-54 is independent of these factors, which provides an effective method to evaluate the cosmogenic contribution to Cr-53 by monitoring the cosmogenic variations in epsilon Cr-54 in meteoritic irons. The results are compared with modeling results that yield a slightly shallower slope of 3.6 +/- 0.2. Modeling results for the olivine in stony meteorites yield a higher slope (similar to 5.4). However, the previous estimated results for lunar samples (stony targets for comic ray irradiation) exhibit an observably shallower slope (similar to 2.62). The reason for the different slopes is that the production rates of different cosmogenic Cr isotopes in iron meteorites and lunar samples are in different proportions. The differences may not be completely controlled by the higher thermal and epithermal neutron fluencies in lunar samples than in iron meteorites, but instead may largely reflect different radiation geometry between the two. More studies are needed to solve this open question. (C) 2019 Published by Elsevier Ltd.

Recycling of crust into the mantle has left only small remnants at Earth's surface of crust produced within a billion years of Earth formation. Few, if any, of these ancient crustal rocks represent the first crust that existed on Earth. Understanding the nature of the source materials of these ancient rocks and the mechanism of their formation has been the target of decades of geological and geochemical study. This traditional approach has been expanded recently through the ability to simultaneously obtain U-Pb age and initial Hf isotope data for zircons from many of these ancient, generally polymetamorphic, rocks. The addition of information from the short-lived radiometric systems Sm-146-Nd-142 and Hf-182-W-182 allows resolution of some of the ambiguities that have clouded the conclusions derived from the long-lived systems. The most apparent of these is clear documentation that Earth experienced major chemical differentiation events within the first tens to hundreds of millions of years of its formation, and that Earth's most ancient crustal rocks were derived from these differentiated sources, not from primitive undifferentiated mantle. Eoarchean rocks from the North Atlantic Craton and the Anshan Complex of the North China Craton have sources in an incompatible-element-depleted mantle that dates to 4.4-4.5 Ga. Hadean/Eoarchean rocks from two localities in Canada show the importance of remelting of Hadean mafic crust to produce Eoarchean felsic crust. The mafic supracrustal rocks of the Nuvvuagittuq Greenstone Belt are a possible example of the Hadean mafic basement that is often called upon to serve as the source for the high-silica rocks that define continental crust. Many, but not all, ancient terranes show a shift in the nature of the sources for crustal rocks, and possibly the physical mechanism of crust production, between 3.0-3.6 Ga. This transition may reflect the initiation of modern plate tectonics. Eoarchean/Hadean rocks from some terranes, however, also display compositional characteristics expected for convergent margin volcanism suggesting that at least some convergent margin related magmatism began in the Hadean. The persistence of isotopic variability in Nd-142/Nd-144 into the mid-Archean, and the eventual reduction in that variability by the end of the Archean, provides new information on the efficiency by which mantle convection recombined the products of Hadean silicate-Earth differentiation. The rate of crust production and recycling in the Hadean/Archean, however, is not resolved by these data beyond the observation that extreme isotopic compositions, such as expected for Hadean evolved, continent-like, crust are not observed in the preserved Eoarchean rock record. The lack of correlation between Nd-142/Nd-144 and W-182/W-184 variation in Archean rocks suggests that these two systems track different processes; the Sm-Nd system mantle-crust differentiation while Hf-W is dominated by core formation. The major silicate differentiation controlling Sm/Nd fractionation occurred at similar to 4.4 Ga, possibly as a result of the Moon-forming impact, after the extinction of Hf-182.

A new collection of spinel-peridotite xenoliths from Quaternary basaltic centers in the Tariat region of Mongolia provide a sample of the shallow lithospheric mantle beneath this area. Ninety-seven of these xenoliths were analyzed for whole rock and mineral major element composition. Both orthopyroxenes and clinopyroxenes separated from the samples were analyzed for trace element content. For a selection of samples, whole rocks were analyzed for trace element contents and clinopyroxenes for the isotopic composition of Sr, Nd, Hf, and Pb. A number of the whole rocks also were analyzed for their Re-Os systematics.

One requirement for isotope ratio measurement results with small measurement uncertainties is that the element of interest is effectively separated from the sample matrix. Efficient chemical separation of W from matrix components, especially Ti, can be challenging, particularly for large test portion masses (>1g). We present a new W separation procedure that takes advantage of the distinct complexation behaviour of Ti and W with citrate ligand in a moderately low pH, oxidising solution. This preparation procedure can reduce the Ti/W ratio of large (4-10g) basaltic (i.e., high-matrix) test portions by a factor of 10(5), relative to their original compositions, in a two-step separation procedure. The procedure additionally provides a separate, well-purified Mo fraction. We show that optimal separation requires precise selection of reagent concentrations and sample load. The procedure was employed to determine the W-182 composition of BHVO-2 as -6.7 +/- 4.2 (2 standard deviation, 2s). The principles derived from this method may prove useful for chemical separation of other elements used for geochemical and cosmochemical applications given an appropriate selection of organic acid. Future successful applications of this method may reveal that the use of organic acids as procedural reagents is a currently under-utilised tool for efficient chemical separation protocols.

The stable isotope compositions of chromium (Cr) are fractionated during magmatic differentiation of lunar mare basalts, which might be attributed to redox-related mineral crystallization. It has yet to be demonstrated whether magmatic differentiation fractionates Cr isotope composition of terrestrial samples. Here, we present high-precision stable Cr isotope measurements, reported as delta Cr-53 relative to NIST SRM 979, of well-characterized Hawaiian tholeiitic basalts from Koolau, Mauna Kea and Kilauea. The studied Makapuu-stage Koolau lavas have MgO ranging from 6.58 to 21.54 wt.%, and they have homogeneous delta Cr-53 ranging from -0.21 parts per thousand to -0.17 parts per thousand. Similarly, studied Mauna Kea lavas have MgO ranging from 9.11 to 17.90 wt.%, and they also have homogeneous delta Cr-53 ranging from -0.17 to -0.13 parts per thousand. Some Makapuu-stage Koolau and Mauna Kea lavas experienced subaerial or submarine alteration. The homogenous delta Cr-53 within each sample suites implies that the post-magmatic alterations have not significantly changed the Cr isotope compositions of these samples. Conversely, nine Kilauea Iki basalts have MgO ranging from 7.77 to 26.87 wt.% reflecting varying degrees of magmatic differentiation, and they show resolvable Cr isotope variations with delta Cr-53 ranging from -0.18 parts per thousand to 0.00 parts per thousand. The delta Cr-53 values of the Kilauea Iki samples are positively correlated with indicators of magmatic differentiation such as Cr and MgO contents, and Mg# values. The most evolved samples have the lightest isotope compositions, whereas the olivine-spinel cumulates display complementary heavy isotope compositions. This fractionation is most likely generated by the crystallization and accumulation of spinel, which is dominated by Cr3+ and, hence, enriched in heavier Cr isotopes relative to the residual melt. At a given MgO content, Kilauea and Mauna Kea lavas, both Kea-trend volcanoes, have higher delta Cr-53 than Makapuu-stage Koolau lavas, a Loa-trend volcano. This difference might reflect recycling of altered oceanic crusts or redox differences of their magmatic sources, with the mantle source of Makapuu-stage lavas being more reducing.