Surface deformation accompanying dike intrusions is dominated by uplift and horizontal motion directly related to the intrusions. In some cases, it includes subsidence due to associated magma reservoir deflation. When reservoir deflation is large enough, it can form, or reactivate preexisting, caldera ring-faults. Ring-fault reactivation, however, is rarely observed during moderate-sized eruptions. On February 21, 2015 at Ambrym volcano in Vanuatu, a basaltic dike intrusion produced more than 1 m of coeruptive uplift, as measured by InSAR, synthetic aperture radar correlation, and Multiple Aperture Interferometry. Here, we show that an average of similar to 40 cm of slip occurred on a normal caldera ring-fault during this moderate-sized (VEI < 3) event, which intruded a volume of similar to 24 x 10(6) m(3) and erupted similar to 9.3 x 10(6) m(3) of lava (DRE). Using the 3D Mixed Boundary Element Method, we explore the stress change imposed by the opening dike and the depressurizing reservoir on a passive, frictionless fault. Normal fault slip is promoted when stress is transferred from a depressurizing reservoir beneath one of Ambrym's main craters. After estimating magma compressibility, we provide an upper bound on the critical fraction (f = 7%) of magma extracted from the reservoir to trigger fault slip. We infer that broad basaltic calderas may form in part by hundreds of subsidence episodes no greater than a few meters, as a result of magma extraction from the reservoir during moderate-sized dike intrusions.

Despite being a widespread and common process, the impact of passive volcanic degassing on the pressurization state of a magma reservoir is not well understood. If mass loss due to gas emissions results in reservoir depressurization and surface subsidence, the pressure difference between a shallow reservoir and deep magma source may result in magma recharge and eventually trigger an eruption. It is therefore important to determine how a simplified reservoir-conduit system responds to such degassing processes. Here we use an extreme example of persistent volcanic degassing-Ambrym-as a case study to relate sulphur dioxide mass flux with reservoir depressurization and edifice-scale subsidence, both measured from satellite-based remote sensing observations. A geodetic inversion of surface displacements measured with Interferometric Synthetic Aperture Radar modeled using the Boundary Element Method provides bounds on the reservoir pressure change during an episode of subsidence at Ambrym from 2015 to 2017. These results are input into a lumped parameter theoretical model developed by Girona et al. (2014), and the free parameters (e.g., reservoir size and conduit radius) are systematically explored. We find that the 2015-2017 subsidence episode is consistent with pressure decreasing at a rate of -5.2 to -2.0 MPa year-1 in a reservoir at ~2 km b.s.l., as a result of passive degassing. The subsidence episode is observed to end abruptly in October 2017, and no significant deformation is detected in the 14 months leading up to a rift zone intrusion and submarine eruption in December 2018, despite substantial degassing. We explain this lack of pre-eruptive deformation by an influx of ~0.16 km3 of magma into a shallow (< 2 km b.s.l.) reservoir that counterbalances the depressurization caused by degassing. This recharge volume is comparable with the volume of magma subsequently extracted from Ambrym's reservoir in December 2018. We conclude that at some open-vent passively degassing volcanoes, deflation caused by degassing may reduce or even cancel any inflation signal caused by magma influx. Nonetheless, detection of pre -eruptive recharge can be achieved by monitoring changes in the long-term deformation rate. (C)& nbsp;2022 Elsevier B.V. All rights reserved.

Photometric observations of occultations of transiting exoplanets can place important constraints on the thermal emission and albedos of their atmospheres. We analyse photometric measurements and derive geometric albedo (A(g)) constraints for five hot Jupiters observed with TESS in the optical: WASP-18 b, WASP-36 b, WASP-43 b, WASP-50 b, and WASP-51 b. For WASP-43 b, our results are complemented by a VLT/HAWK-I observation in the near-infrared at 2.09 mu m. We derive the first geometric albedo constraints for WASP-50 b and WASP-51 b: A(g) < 0.445 and A(g) < 0.368, respectively. We find that WASP-43 b and WASP-18 b are both consistent with low geometric albedos (A(g) < 0.16) even though they lie at opposite ends of the hot Jupiter temperature range with equilibrium temperatures of similar to 1400 K and similar to 2500 K, respectively. We report self-consistent atmospheric models that explain broad-band observations for both planets from TESS, HST, Spitzer, and VLT/HAWK-I. We find that the data of both hot Jupiters can be explained by thermal emission alone and inefficient day-night energy redistribution. The data do not require optical scattering from clouds/hazes, consistent with the low geometric albedos observed.

Volatile abundances in lunar mantle are critical factors to consider for constraining the model of Moon formation. Recently, the earlier understanding of a "dry" Moon has shifted to a fairly "wet" Moon due to the detection of measurable amount of H2O in lunar volcanic glass beads, mineral grains, and olivine-hosted melt inclusions. The ongoing debate on a "dry" or "wet" Moon requires further studies on lunar melt inclusions to obtain a broader understanding of volatile abundances in the lunar mantle. One important uncertainty for lunar melt inclusion studies, however, is whether the homogenization of melt inclusions would cause volatile loss. In this study, a series of homogenization experiments were conducted on olivine-hosted melt inclusions from the sample 74220 to evaluate the possible loss of volatiles during homogenization of lunar melt inclusions. Our results suggest that significant loss of H2O could occur even during minutes of homogenization, while F, Cl and S in the inclusions remain unaffected.

Earth's Moon was thought to be highly depleted in volatiles due to its formation by a giant impact. Over the last decade, however, evidence has been found in apatites, lunar volcanic glass beads, nominally anhydrous minerals and olivine-hosted melt inclusions, to support a relatively "wet" Moon. In particular, based on H2O/Ce, F/Nd, and S/Dy ratios, recent melt inclusion (MI) work estimated volatile (H2O, F, and S) abundances in lunar rocks to be similar to or slightly lower than the terrestrial depleted mantle. Uncertainties still occur, however, in whether the limited numbers of lunar samples studied are representative of the primitive lunar mantle, and whether the high H2O/Ce ratio for pyroclastic sample 74220 is due to local heterogeneity. In this paper, we report major element, trace element, volatile, and transition metal data in MIs for 5 mare basalt samples (10020, 12040, 15016, 15647 and 74235) and a pyroclastic deposit (74220).

Graphite capsules are commonly used in high-temperature, high-pressure experiments, particularly for nominally anhydrous experiments and iron-bearing silicate samples. Due to the presence of graphite in the sample assembly, the oxygen fugacity for these experiments is thought to be relatively low, typically at or below the graphite-CO-CO2 buffer (CCO). The detailed mechanism and kinetics of redox control in graphite capsule experiments are, however, poorly understood. This is especially problematic for short duration experiments (e.g. kinetic experiments), because it is uncertain whether the experimental product will preserve its initial oxygen fugacity, or become reduced during the experiment. In this study, a set of basaltic glasses after high-temperature experiments in graphite capsules were analyzed by micro X-ray absorption near-edge structure (mu-XANES) to obtain their Fe3+/sigma Fe profiles near the graphite-melt interface. The results show rapid reduction of ferric iron in the basaltic melt, reaching near-equilibrium in half an hour for samples of 2 mm diameter and 1.3-1.9 mm thickness. Even for a "time-zero" experiment, which was quenched immediately after reaching the target temperature, the reduction profile is over 100 mu m in length. By comparing experiments at the same temperature and pressure but with different durations, the reduction reaction progress is found to be linear to the square root of duration, indicating that the reduction process is diffusion-controlled. Such a rapid reduction of the basaltic melt requires a mechanism that is significantly faster than divalent cation diffusion or oxygen diffusion, and is best explained by molecular hydrogen diffusion. It has been shown by previous studies that nominally anhydrous high-pressure experiments could contain significant amounts of water. Thousands of ppm of H2O could remain in the graphite capsule even after drying at 120 degrees C for an extended time period. At high temperatures, H2O reacts with graphite to produce molecular hydrogen, which then diffuses into the basaltic glass and causes reduction. This mechanism is also supported by a compensating H2O profile of equivalent length in the basaltic glass, showing evidence for H2O produced by molecular hydrogen reacting with ferric iron. A quantitative model is proposed and it successfully reproduces the Fe3+/sigma Fe profiles in our experiments. The model helps explain the kinetics of the reduction process and demonstrates that for a basaltic glass with reasonable initial FeO* content, Fe3+/sigma Fe ratios, and thicknesses, the equilibrium oxidation state can usually be reached in one hour at similar to 1300 degrees C and similar to 0.5 GPa. Although extrapolating our conclusion to the large range of graphite capsule experiments requires knowledge on how H-2 solubility and diffusivity varies as a function of silicate composition, temperature, and pressure, the reduction process is expected to be rapid in general because H-2 diffusivity is high in silicate melts. Our study elucidates the mechanism and rate of oxygen fugacity change in graphite capsule experiments. Based on thermodynamic calculations, the reaction between graphite capsule and H2O is expected to produce a C-O-H fluid with an intrinsic oxygen fugacity of CCO -0.

High-pressure COH fluids have a fundamental role in a variety of geological processes. Their composition in terms of volatile species can control the solidus temperature and carbonation/decarbonation reactions, as well as influence the amount of solutes generated during fluid-rock interaction at depth. Over the last decades, several systems have been experimentally investigated to unravel the effect of COH fluids at upper-mantle conditions. However, fluid composition is rarely tackled as a quantitative issue, and rather infrequently fluids are analyzed in the same way as the associated solid phases in the experimental assemblage. A comprehensive characterization of carbon-bearing aqueous fluids in terms of composition is hampered by experimental difficulties in synthetizing and analyzing high-pressure fluids without altering their composition upon quenching.