Metamorphism is thought to destroy microfossils, partly through devolatilization and graphitization of biogenic organic matter. However, the extent to which there is a loss of molecular, elemental and isotope signatures from biomass during high-temperature metamorphism is not clearly established. We report on graphitic structures inside and coating apatite grains from the c. 1850 Ma Michigamme silicate banded iron formation from Michigan, metamorphosed above 550 degrees C. Traces of N, S, O, H, Ca and Fe are preserved in this graphitic carbon and X-ray spectra show traces of aliphatic groups. Graphitic carbon has an expanded lattice around 3.6 angstrom, forms microscopic concentrically-layered and radiating polygonal flakes and has homogeneous delta C-13 values around -22 parts per thousand, identical to bulk analyses. Graphitic carbon inside apatite is associated with nanometre-size ammoniated phyllosilicate. Precursors of these metamorphic minerals and graphitic carbon originated from ferruginous clay-rich sediments with biomass. We conclude that graphite coatings and inclusions in apatite grains indicate fluid remobilization during amphibolite-facies metamorphism of precursor biomass. This new evidence fills in observational gaps of metamorphosed biomass into graphite and supports the existence of biosignatures in the highly metamorphosed iron formation from the Eoarchean Akilia Association, which dates from the beginning of the sedimentary rock record.

We report Mo isotopic compositions of 37 presolar SiC grains of types Y (19) and Z (18), rare types commonly argued to have formed in lower-than-solar metallicity asymptotic giant branch (AGB) stars. Direct comparison of the Y and Z grain data with data for mainstream grains from AGB stars of close-to-solar metallicity demonstrates that the three types of grains have indistinguishable Mo isotopic compositions. We show that the Mo isotope data can be used to constrain the maximum stellar temperatures (T-MAX) during thermal pulses in AGB stars. Comparison of FRUITY Torino AGB nucleosynthesis model calculations with the grain data for Mo isotopes points to an origin from low-mass (similar to 1.5-3 M-circle dot) rather than intermediate-mass (> 3-similar to 9 M-circle dot) AGB stars. Because of the low efficiency of Ne-22(alpha, n)Mg-25 at the low T-MAX values attained in low-mass AGB stars, model calculations cannot explain the large Si-30 excesses of Z grains as arising from neutron capture, so these excesses remain a puzzle at the moment.

Here we report the relative degrees of thermal metamorphism for five Antarctic Ornans-like carbonaceous (CO) chondrites, including Dominion Range (DOM) 08006, as determined from the Cr-content of their FeO-rich (ferroan) olivine. These five CO3 chondrites complete the previously poorly-defined CO3.00 to 3.2 chondrite metamorphic trend. DOM 08006 appears to be a highly primitive CO chondrite of petrologic type 3.00. We report the detailed mineralogy and petrography of DOM 08006 using a coordinated, multi-technique approach.

The explosion mechanism of electron-capture supernovae (ECSNe) remains equivocal: it is not completely clear whether these events are implosions in which neutron stars are formed, or incomplete thermonuclear explosions that leave behind bound ONeFe white dwarf remnants. Furthermore, the frequency of occurrence of ECSNe is not known, though it has been estimated to be of the order of a few per cent of all core-collapse supernovae. We attempt to constrain the explosion mechanism (neutron-star-forming implosion or thermonuclear explosion) and the frequency of occurrence of ECSNe using nucleosynthesis simulations of the latter scenario, population synthesis, the solar abundance distribution, pre-solar meteoritic oxide grain isotopic ratio measurements and the white dwarf mass-radius relation. Tracer particles from the 3d hydrodynamic simulations were post-processed with a large nuclear reaction network in order to determine the complete compositional state of the bound ONeFe remnant and the ejecta, and population synthesis simulations were performed in order to estimate the ECSN rate with respect to the CCSN rate. The 3d deflagration simulations drastically overproduce the neutron-rich isotopes Ca-48, Ti-50, Cr-54, Fe-60 and several of the Zn isotopes relative to their solar abundances. Using the solar abundance distribution as our constraint, we place an upper limit on the frequency of thermonuclear ECSNe as 1-3% the frequency at which core-collapse supernovae (FeCCSNe) occur. This is on par with or 1 dex lower than the estimates for ECSNe from single stars. The upper limit from the yields is also in relatively good agreement with the predictions from our population synthesis simulations. The Cr-54/Cr-52 and Ti-50/Ti-48 isotopic ratios in the ejecta are a near-perfect match with recent measurements of extreme pre-solar meteoritc oxide grains, and Cr-53/Cr-52 can also be matched if the ejecta condenses before mixing with the interstellar medium. The composition of the ejecta of our simulations implies that ECSNe, including accretion-induced collapse of oxygen-neon white dwarfs, could actually be partial thermonuclear explosions and not implosions that form neutron stars. There is still much work to do to improve the hydrodynamic simulations of such phenomena, but it is encouraging that our results are consistent with the predictions from stellar evolution modelling and population synthesis simulations, and can explain several key isotopic ratios in a subset of pre-solar oxide meteoritic grains. Theoretical mass-radius relations for the bound ONeFe WD remnants of these explosions are apparently consistent with several observational WD candidates. The composition of the remnants in our simulations can reproduce several, but not all, of the spectroscopically-determined elemental abundances from one such candidate WD.

In this study we investigate the likeliness of the existence of an iron sulfide layer (FeS matte) at the core-mantle boundary (CMB) of Mercury by comparing new chemical surface data obtained by the X-ray Spectrometer onboard the MESSENGER spacecraft with geochemical models supported by high-pressure experiments under reducing conditions. We present a new data set consisting of 233 Ti/Si measurements, which combined with Al/Si data show that Mercury's surface has a slightly subchondritic Ti/Al ratio of 0.035 +/- 0.008. Multiphase equilibria experiments show that at the conditions of Mercury's core formation, Ti is chalcophile but not siderophile, making Ti a useful tracer of sulfide melt formation. We parameterize and use our partitioning data in a model to calculate the relative depletion of Ti in the bulk silicate fraction of Mercury as a function of a putative FeS layer thickness. By comparing the model results and surface elemental data we show that Mercury most likely does not have a FeS layer, and in case it would have one, it would only be a few kilometers thick (<13 km). We also show that Mercury's metallic Fe(Si) core cannot contain more than similar to 1.5 wt.% sulfur and that the formation of this core under reducing conditions is responsible for the slightly subchondritic Ti/Al ratio of Mercury's surface. (C) 2020 Elsevier B.V. All rights reserved.

Meteorites originating from primitive C-type asteroids are composed of materials from the Sun's protoplanetary disk, including up to a few per cent organic carbon. In contrast, some interplanetary dust particles and micrometeorites have much higher carbon contents, up to >90%, and are thought to originate from icy outer Solar System bodies and comets. Here we report an approximately 100-mu m-diameter very carbon-rich clast, with highly primitive characteristics, in the matrix of a CR2 chondrite, LaPaz Icefield 02342. The clast may represent a cometary building block, largely unsampled in meteorite collections, that was captured by a C-type asteroid during the early stages of planet formation. The existence of this cometary microxenolith supports the idea of a radially inward transport of materials from the outer protoplanetary disk into the CR chondrite reservoir during the formation of planetesimals. Moreover, the H-isotopic composition of the clast is suggestive of a temporal evolution of organic isotopic compositions in the comet-forming region of the disk.