Scientific ocean drilling cores recovered years ago (legacy cores), especially as recovered by rotary drilling, commonly show incomplete recovery and core disturbance. We present a novel method to date such cores by presenting the first high-precision U-Pb zircon ages targeting the duration of the Miocene Climate Optimum (MCO; ca. 17-14 Ma) from volcanic ashes at Ocean Drilling Program Site 1000 (on the Nicaragua Rise in the Caribbean Sea). We place these ages within a newly developed framework to address incomplete core recovery and use them to calibrate a high-resolution bulk carbonate 6 13 C and 6 18 O record. Our Site 1000 ages show that volcanism of the Columbia River Basalt Group (CRBG) large igneous province was coincident with the interval of greatest sustained MCO warmth at this site. However, if the CRBG were the primary driver of the MCO, our chronology may allow for outgassing preceding volcanism as a major source of CO 2 . We thus document a promising new way to obtain highly resolved, accurate, and precise numerical age models for legacy deep-sea sediment cores that does not depend on correlation to other records.

Ukraine supplies a large proportion of grain and oilseeds to the world market and faces disruptions from the Russian invasion in 2022. Here we explore the combined effects of the invasion and climate change on Ukraine's irrigation. In 2021, only 1.6% of Ukraine's cropland was irrigated. Of this portion, 73% experienced substantial declines in irrigated crop production following the invasion. We estimate that by the mid-twenty-first century, three-quarters of croplands will experience water shortages, making business-as-usual rain-fed agricultural practices inadequate in addressing the challenges posed by climate change. We explore how leveraging local surface and groundwater resources could enable sustainable irrigation expansion over 18millionhectares of croplands and form a viable climate adaptation strategy. Finally, we identify regions for implementing enhancements or expansions of irrigation systems that can foster a more resilient agricultural sector-underscoring the growing importance of irrigation in sustaining crop production in Ukraine.

The germanosilicide Na4-xGeySi16-y (0.4 ≤ x ≤ 1.1, 4.7 ≤ y ≤ 9.3) was synthesized under high-pressure, high-temperature conditions. The novel guest-host compound comprises a unique tetrel framework with dual channels housing sodium and smaller, empty (Si,Ge)9 units. The arrangement represents a new structure type with an overall structural topology that is closely related to a hypothetical carbon allotrope. Topological analysis of the structure revealed that the guest environment space cannot be tiled with singular polyhedra as in cage compounds (e.g., clathrates). The analysis of natural tilings provides a convenient method to unambiguously compare related tetrel-rich structures and can help elucidate new possible structural arrangements of intermetallic compounds.

To what extent are naturally evolving systems limited in their potential diversity (i.e. "bounded") versus unrestricted ("open-ended")? Minerals provide a quantitative model evolving system, with well-documented increases in mineral diversity through multiple stages of planetary evolution over billions of years. A recent framework that unifies behaviors of both biotic and abiotic evolving systems posits that all such systems are characterized by combinatorial richness subject to selection. In the case of minerals, combinatorial richness derives from the possible combinations of chemical elements coupled with permutations of their formulas' coefficients. Observed mineral species, which are selected for persistence through deep time, represent a miniscule fraction of all possible element configurations. Furthermore, this model predicts that as planetary systems evolve, stable minerals become an ever-smaller fraction of the "possibility space." A postulate is that "functional information," defined as the negative log2 of that fraction, must increase as a system evolves. We have tested this hypothesis for minerals by estimating the fraction of all possible chemical formulas observed from one stage of mineral evolution to the next, based on numbers of different essential elements and the maximum chemical formula complexity at each of nine chronological stages of mineral evolution. We find a monotonic increase in mineral functional information through these nine stages-a result consistent with the hypothesis. Furthermore, analysis of the chemical formulas of minerals demonstrates that the modern Earth may be approaching the maximum limit of functional information for natural mineral systems-a result demonstrating that mineral evolution is not open-ended.

Giant exoplanets orbiting close to their host stars are unlikely to have formed in their present configurations1. These 'hotJupiter' planets are instead thought to have migrated inward from beyond the ice line and several viable migration channels have been proposed, including eccentricity excitation through angular-momentum exchange with a third body followed by tidally driven orbital circularization2,3. The discovery of the extremely eccentric (e=0.93) giant exoplanet HD80606b (ref.4) provided observational evidence that hot Jupiters may have formed through this high-eccentricity tidal-migration pathway5. However, no similar hot-Jupiter progenitors have been found and simulations predict that one factor affecting the efficacy of this mechanism is exoplanet mass, as low-mass planets are more likely to be tidally disrupted during periastron passage6-8. Here we present spectroscopic and photometric observations of TIC241249530b, a high-mass, transiting warm Jupiter with an extreme orbital eccentricity of e=0.94. The orbit of TIC241249530b is consistent with a history of eccentricity oscillations and a future tidal circularization trajectory. Our analysis of the mass and eccentricity distributions of the transiting-warm-Jupiter population further reveals a correlation between high mass and high eccentricity.

Exoplanet demographics are sufficiently advanced to provide important constraints on theories of planet formation. While core and pebble accretion are preferred for rocky and icy planets, there appears to be a need for gas disk gravitational instability (GDGI) to play a role in the formation of M-dwarf gas giants and those orbiting at large distances. Here we present GDGI models that go beyond those presented by Boss (2011) dealing with the formation of wide-orbit gas giants. The new models use quadrupled spatial resolution, in both the radial and azimuthal directions, to reduce the effects of finite spatial resolution. The new models also employ the beta cooling approximation, instead of the diffusion approximation used by Boss (2011), in order to push the models further in time. As in Boss (2011), the central protostars have masses of 0.1, 0.5, 1.0, 1.5, or 2.0 M circle dot, surrounded by disks with masses ranging from 0.019 M circle dot to 0.21 M circle dot. For each case, two models are computed, one with an initial minimum Toomre Q stability value ranging from 1.1 to 1.7, and one with a higher initial disk temperature, resulting in the initial minimum Q ranging from 2.2 to 3.4. These new models continue to show that GDGI can explain the formation of gas giants at distances of similar to 30 to similar to 50 au on eccentric orbits (e less than similar to 0.2), though the number formed drops to 0 as the protostar mass decreases to 0.1 M circle dot.

Discovering transiting exoplanets with relatively long orbital periods (>10 d) is crucial to facilitate the study of cool exoplanet atmospheres (T-eq < 700 K) and to understand exoplanet formation and inward migration further out than typical transiting exoplanets. In order to discover these longer period transiting exoplanets, long-term photometric, and radial velocity campaigns are required. We report the discovery of TOI-2447 b (=NGTS-29 b), a Saturn-mass transiting exoplanet orbiting a bright (T = 10.0) Solar-type star (T-eff = 5730 K). TOI-2447 b was identified as a transiting exoplanet candidate from a single transit event of 1.3 per cent depth and 7.29 h duration in TESS Sector 31 and a prior transit event from 2017 in NGTS data. Four further transit events were observed with NGTS photometry which revealed an orbital period of P = 69.34 d. The transit events establish a radius for TOI-2447 b of 0.865 +/- 0.010 R-J, while radial velocity measurements give a mass of 0.386 +/- 0.025 M-J. The equilibrium temperature of the planet is 414 K, making it much cooler than the majority of TESS planet discoveries. We also detect a transit signal in NGTS data not caused by TOI-2447 b, along with transit timing variations and evidence for a similar to 150 d signal in radial velocity measurements. It is likely that the system hosts additional planets, but further photometry and radial velocity campaigns will be needed to determine their parameters with confidence. TOI-2447 b/NGTS-29 b joins a small but growing population of cool giants that will provide crucial insights into giant planet composition and formation mechanisms.

We have used a combined sample of JADES and CEERS objects in order to constrain ionizing photon production efficiency (ξion) from JWST /NIRSpec and JWST /NIRCam data. We examine 163 objects at 1.06 < z < 6.71 with significant (3σ) spectroscopic detections of Hα and Hβ in order to constrain intrinsic Hα luminosities corrected from nebular dust attenuation via Balmer decrements. We constrain dust-corrected UV luminosities from best-fit spectral-energy distribution modeling. We find a sample median log10(ξion,0/erg Hz−1) ) = 25.29−0.37+0.29, assuming fesc=0  for the escape fraction of Lyman continuum emission. We find significant correlation between ξ ion,0 and z, with objects at z > 4.64 having median log10(ξion,0/erg Hz−1) = 25.38−0.38+0.38, with those below having log10(ξion,0/ergHz−1) = 25.24−0.33+0.30.  We also find significant, positive correlations between ξion,0 and LUV; Wλ([O III]); [O III]λ5007/[O II] λλ3726, 3729; and inverse correlations with metallicity. In contrast with some previous results, we find no trends between ξion,0 and stellar mass, stellar dust attenuation, or UV slope. Applying a multivariate fit to ξion,0, z, and MUV to an empirically-motivated model of reionization, and folding in fesc estimates from direct observations of the Lyman continuum at z ∼ 3 from the Keck Lyman Continuum Spectroscopic survey, we find that the number of ionizing photons entering the IGM causes reionization to end at z ∼ 5 − 7.

Tidal disruption events (TDEs) can potentially probe low-mass black holes in host galaxies that might not adhere to bulge or stellar-dispersion relationships. At least initially, TDEs can also reveal sup er-Eddington accretion. X-ray spectroscopy can potentially constrain black hole masses, and reveal ionized outflows associated with sup er-Eddington accretion. Our analysis of XMM-Newton X-ray observations of the TDE AT2021ehb, around 300 days post-disruption, reveals a soft spectrum and can be fit with a combination of multi-color disk blackbody and power-law components. Using two independent disk models with properties suited to TDEs, we estimate a black hole mass at M ≃ 10.5 M⊙ , indicating AT2021ehb may expose the elusive low-mass end of the nuclear black hole population. These models offer simple yet robust characterization; more complicated models are not required, but provide important context and caveats in the limit of moderately sensitive data. If disk reflection is included, the disk flux is lower and inferred black hole masses are ∼ 0.35 dex higher. Simple wind formulations imply an extremely fast vout = −0 . 2 c outflow and obviate a disk continuum component. Assuming a unity filling factor, such a wind implies an instantaneous mass outflow rate of M ˙ ≃ 5 M ⊙ yr−1.Such a high rate suggests that the filling factor for the Ultra Fast Outflow (UFO) must be extremely low, and/or the UFO phase is ephemeral. We discuss the strengths and limitations of our analysis and avenues for future observations of TDEs.