The ability to infer ocean chlorophyll-a concentrations (Chla) from spaceborne instruments is key to assessments of global ocean productivity and monitoring of water quality. Here, we present a novel parametric algorithm, OCG, trained on a set of global in situ high-performance liquid chromatography (HPLC) data that leverages Level3 remote sensing reflectance (Rrs) products from the Moderate Resolution Imaging Spectroradiometer (MODIS) aboard the Aqua satellite. The OCG algorithm leverages more bands than existing algorithms and also provides pixel-wise uncertainty assessments that enable the calculation of the probability of exceeding specific Chla thresholds. This feature has significant implications for water quality management, particularly in monitoring harmful algal blooms. The OCG surpasses existing algorithms in bias and accuracy without overfitting, especially in coastal areas, where it outperforms the current standard product (CI OC3) by 20 % in median symmetric accuracy. Moreover, the OCG reduces the signed symmetric percentage bias (SSPB) in coastal regions from 41 % (CI OC3) to below 5 %. Globally, the OCG algorithm yields lower Chla in coastal regions, the Southern Ocean and the Mediterranean Sea, and higher values in the open ocean, particularly in ocean gyres and polar regions. For the Chesapeake Bay and the Baltic Sea, for example, daily OCG estimates for 2002 to 2021 are, on average, 2.9 g/ L and 3.7 g/L lower than CI OC3 estimates, respectively. The presented approach also shows great potential for other existing and upcoming sensors, enabling widespread application in remote sensing.

Most galaxies, including the Milky Way, harbor a central supermassive black hole (SMBH) weighing millions to billions of solar masses. Surrounding these SMBHs are dense regions of stars and stellar remnants, such as neutron stars (NSs) and black holes (BHs). NSs and possibly BHs receive large natal kicks at birth on the order of hundreds of kilometers per second. The natal kicks that occur in the vicinity of an SMBH may redistribute the orbital configuration of the compact objects and alter their underlying density distribution. We model the effects of natal kicks on a Galactic center (GC) population of massive stars and stellar binaries with different initial density distributions. Using observational constraints from stellar orbits near the GC, we place an upper limit on the steepness of the initial stellar profile and find it to be core-like. In addition, we predict that 30%-70% of compact objects become unbound from the SMBH due to their kicks and will migrate throughout the Galaxy. Different BH kick prescriptions lead to distinct spatial and kinematic distributions. We suggest that the Nancy Grace Roman Space Telescope may be able to distinguish between these distributions and thus be able to differentiate between natal kick mechanisms.

Primitive arc magmas are more oxidized and enriched in sulfur-34 (S-34) compared to mid-ocean ridge basalts. These findings have been linked to the addition of slab-derived volatiles, particularly sulfate, to arc magmas. However, the oxidation state of sulfur in slab fluids and the mechanisms of sulfur transfer in the slab remain inconclusive. Juxtaposed serpentinite and eclogitic metagabbro from the Voltri Massif (Italy) provide evidence for sulfur mobilization and associated redox processes during infiltration of fluids. Using bulk rock and in situ delta S-34 measurements, combined with thermodynamic calculations, we document the transfer of bisulfide-dominated, S-34-enriched fluids in equilibrium with serpentinite into adjacent metagabbro. We argue that the process documented in this study is pervasive along the subduction interface and infer that subsequent melting of these reacted slab-mantle interface rocks could produce melts that display the characteristic oxygen fugacity and sulfur isotope signatures of arc magmas worldwide.

Nitrite is a central molecule in the nitrogen cycle because nitrite oxidation to nitrate (an aerobic process) retains fixed nitrogen in a system and its reduction to dinitrogen gas (anaerobic) reduces the fixed nitrogen inventory. Despite its acknowledged requirement for oxygen, nitrite oxidation is observed in oxygen-depleted layers of the ocean's oxygen minimum zones (OMZs), challenging the current understanding of OMZ nitrogen cycling. Previous attempts to determine whether nitrite-oxidizing bacteria in the anoxic layer differ from known nitrite oxidizers in the open ocean were limited by cultivation difficulties and sequencing depth. Here, we construct 31 draft genomes of nitrite-oxidizing bacteria from global OMZs. The distribution of nitrite oxidation rates, abundance and expression of nitrite oxidoreductase genes, and relative abundance of nitrite-oxidizing bacterial draft genomes from the same samples all show peaks in the core of the oxygen-depleted zone (ODZ) and are all highly correlated in depth profiles within the major ocean oxygen minimum zones. The ODZ nitrite oxidizers are not found in the Tara Oceans global dataset (the most complete oxic ocean dataset), and the major nitrite oxidizers found in the oxygenated ocean do not occur in ODZ waters. A pangenomic analysis shows the ODZ nitrite oxidizers have distinct gene clusters compared to oxic nitrite oxidizers and are microaerophilic. These findings all indicate the existence of nitrite oxidizers whose niche is oxygen-deficient seawater. Thus, specialist nitrite-oxidizing bacteria are responsible for fixed nitrogen retention in marine oxygen minimum zones, with implications for control of the ocean's fixed nitrogen inventory.

Extensive reservoir construction has fragmented more than 70% of the world's rivers, significantly impacting river connectivity and carbon cycling. However, the response of riverine dissolved organic matter (DOM) to reservoir influence and its potential downstream effects remains unclear. In this study, we employed multiple analytical techniques, including Fourier transform ion cyclotron resonance mass spectrometry, radiocarbon dating, and environmental factor analysis, to investigate the dynamic changes in DOM and its controlling factors under different hydrological management regimes in the LongTan Reservoir, the largest reservoir in the Pearl River, which is the second largest river in China by water discharge. Our results indicate that the molecular diversity of riverine DOM is reduced in the reservoir. Oxygen-rich and heteroatomic compounds, such as those containing nitrogen, sulfur, and phosphorus, are preferentially removed through enhanced photo- and biodegradation processes in the reservoir, particularly during the storage period. This leads to DOM that is enriched with oxygen-poor compounds and shows a biodegraded Delta 14C value downstream. This study highlights that the composition of riverine DOM is significantly altered by the reservoir, but these effects could potentially be mitigated by optimizing the outlet location.

Planets between the sizes of Earth and Neptune are the most common in the Galaxy, bridging the gap between the terrestrial and giant planets in our solar system. Now that we are firmly in the era of JWST, we can begin to measure, in more detail, the atmospheres of these ubiquitous planets to better understand their evolutionary trajectories. The two planets in the TOI-836 system are ideal candidates for such a study, as they fall on either side of the radius valley, allowing for direct comparisons of the present-day atmospheres of planets that formed in the same environment but had different ultimate end states. We present results from the JWST NIRSpec G395H transit observation of the larger and outer of the planets in this system, TOI-836c (2.587 R-circle plus, 9.6 M-circle plus, T-eq similar to 665 K). While we measure average 30-pixel binned precisions of similar to 24 ppm for NRS1 and similar to 43 ppm for NRS2 per spectral bin, we do find residual correlated noise in the data, which we attempt to correct using the JWST Engineering Database. We find a featureless transmission spectrum for this sub-Neptune planet and are able to rule out atmospheric metallicities <175x solar in the absence of aerosols at less than or similar to 1 mbar. We leverage microphysical models to determine that aerosols at such low pressures are physically plausible. The results presented herein represent the first observation from the COMPASS (Compositions of Mini-Planet Atmospheres for Statistical Study) JWST program, which also includes TOI-836b and will ultimately compare the presence and compositions of atmospheres for 12 super-Earths/sub-Neptunes.

Recent Atacama Large Millimeter/submillimeter Array (ALMA) observations of protoplanetary disks in the millimeter continuum have shown a variety of radial gaps, cavities, and spiral features. These substructures may be signposts for ongoing planet formation, and therefore these systems are promising targets for direct imaging planet searches in the near-infrared. To this end, we present results from a deep imaging survey in the L ' band (3.8 mu m) with the Keck/NIRC2 vortex coronagraph to search for young planets in 43 disks with resolved features in the millimeter continuum or evidence for gaps/central cavities from their spectral energy distributions. Although we do not detect any new point sources, using the vortex coronagraph allows for high sensitivity to faint sources at small angular separations (down to similar to 0.'' 1), allowing us to place strong upper limits on the masses of potential gas giant planets. We compare our mass sensitivities to the masses of planets derived using ALMA observations, and while we are sensitive to similar to 1 M Jup planets in the gaps in some of our systems, we are generally not sensitive to planets of the masses expected from the ALMA observations. In addition to placing upper limits on the masses of gas giant planets that could be interacting with the dust in the disks to form the observed millimeter substructures, we are also able to map the micron-sized dust as seen in scattered light for 8 of these systems. Our large sample of systems also allows us to investigate limits on planetary accretion rates and disk viscosities.

Shock experiments are widely used to understand the mechanical and electronic properties of matter under extreme conditions. However, after shock loading to a Hugoniot state, a clear description of the post-shock thermal state and its impacts on materials is still lacking. We used diffraction patterns from 100-fs x-ray pulses to investigate the temperature evolution of laser-shocked Al-Zr metal film composites at time delays ranging from 5 to 75 ns driven by a 120-ps short-pulse laser. We found significant heating of both Al and Zr after shock release, which can be attributed to heat generated by inelastic deformation. A conventional hydrodynamic model that employs (i) typical descriptions of Al and Zr mechanical strength and (ii) elevated strength responses (which might be attributed to an unknown strain rate dependence) did not fully account for the measured temperature increase, which suggests that other strength-related mechanisms (such as fine-scale void growth) could play an important role in thermal responses under shock wave loading/unloading cycles. Our results suggest that a significant portion of the total shock energy delivered by lasers becomes heat due to defect-facilitated plastic work, leaving less converted to kinetic energy. This heating effect may be common in laser-shocked experiments but has not been well acknowledged. High post-shock temperatures may induce phase transformation of materials during shock release. Another implication for the study is the preservability of magnetic records from planetary surfaces that have a shock history from frequent impact events.

Hydrogen will play a key role in decarbonizing economies. Here, we quantify the costs and environmental impacts of possible large-scale hydrogen economies, using four prospective hydrogen demand scenarios for 2050 ranging from 111-614 megatonne H2 year-1. Our findings confirm that renewable (solar photovoltaic and wind) electrolytic hydrogen production generates at least 50-90% fewer greenhouse gas emissions than fossil-fuel-based counterparts without carbon capture and storage. However, electrolytic hydrogen production could still result in considerable environmental burdens, which requires reassessing the concept of green hydrogen. Our global analysis highlights a few salient points: (i) a mismatch between economical hydrogen production and hydrogen demand across continents seems likely; (ii) region-specific limitations are inevitable since possibly more than 60% of large hydrogen production potentials are concentrated in water-scarce regions; and (iii) upscaling electrolytic hydrogen production could be limited by renewable power generation and natural resource potentials.