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Abstract
Shock experiments are widely used to understand the mechanical and electronic properties of matter under extreme conditions. However, after shock loading to a Hugoniot state, a clear description of the post-shock thermal state and its impacts on materials is still lacking. We used diffraction patterns from 100-fs x-ray pulses to investigate the temperature evolution of laser-shocked Al-Zr metal film composites at time delays ranging from 5 to 75 ns driven by a 120-ps short-pulse laser. We found significant heating of both Al and Zr after shock release, which can be attributed to heat generated by inelastic deformation. A conventional hydrodynamic model that employs (i) typical descriptions of Al and Zr mechanical strength and (ii) elevated strength responses (which might be attributed to an unknown strain rate dependence) did not fully account for the measured temperature increase, which suggests that other strength-related mechanisms (such as fine-scale void growth) could play an important role in thermal responses under shock wave loading/unloading cycles. Our results suggest that a significant portion of the total shock energy delivered by lasers becomes heat due to defect-facilitated plastic work, leaving less converted to kinetic energy. This heating effect may be common in laser-shocked experiments but has not been well acknowledged. High post-shock temperatures may induce phase transformation of materials during shock release. Another implication for the study is the preservability of magnetic records from planetary surfaces that have a shock history from frequent impact events.
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Abstract
Hydrogen will play a key role in decarbonizing economies. Here, we quantify the costs and environmental impacts of possible large-scale hydrogen economies, using four prospective hydrogen demand scenarios for 2050 ranging from 111-614 megatonne H2 year-1. Our findings confirm that renewable (solar photovoltaic and wind) electrolytic hydrogen production generates at least 50-90% fewer greenhouse gas emissions than fossil-fuel-based counterparts without carbon capture and storage. However, electrolytic hydrogen production could still result in considerable environmental burdens, which requires reassessing the concept of green hydrogen. Our global analysis highlights a few salient points: (i) a mismatch between economical hydrogen production and hydrogen demand across continents seems likely; (ii) region-specific limitations are inevitable since possibly more than 60% of large hydrogen production potentials are concentrated in water-scarce regions; and (iii) upscaling electrolytic hydrogen production could be limited by renewable power generation and natural resource potentials.
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Abstract
This second paper presents an in-depth analysis of the composition of the planetary material that has been accreted on to seven white dwarfs with circumstellar dust and gas emission discs with abundances reported in Rogers et al. The white dwarfs are accreting planetary bodies with a wide range of oxygen, carbon, and sulphur volatile contents, including one white dwarf that shows the most enhanced sulphur abundance seen to date. Three white dwarfs show tentative evidence (2-3 sigma) of accreting oxygen-rich material, potentially from water-rich bodies, whilst two others are accreting dry, rocky material. One white dwarf is accreting a mantle-rich fragment of a larger differentiated body, whilst two white dwarfs show an enhancement in their iron abundance and could be accreting core-rich fragments. Whilst most planetary material accreted by white dwarfs display chondritic or bulk Earth-like compositions, these observations demonstrate that core-mantle differentiation, disruptive collisions, and the accretion of core-mantle differentiated material are important. Less than 1 per cent of polluted white dwarfs host both observable circumstellar gas and dust. It is unknown whether these systems are experiencing an early phase in the disruption and accretion of planetary bodies, or alternatively if they are accreting larger planetary bodies. From this work there is no substantial evidence for significant differences in the accreted refractory abundance ratios for those white dwarfs with or without circumstellar gas, but there is tentative evidence for those with circumstellar gas discs to be accreting more water rich material which may suggest that volatiles accrete earlier in a gas-rich phase.
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Conel Alexander
August 16, 2024
Awards

Carnegie Science dominates the Meteoritical Society awards

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August 16, 2024
Awards

Empowering the next generation: CASE alumna receives prestigious $20,000 scholarship

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August 16, 2024
Organizational News

Isotope geochemist Andrea Giuliani joins Carnegie Science as new Staff Scientist

Abstract
We present optical follow-up of IGR J16194-2810, a hard X-ray source discovered by the INTEGRAL mission. The optical counterpart is a similar to 500 L circle dot red giant at a distance of 2.1 kpc. We measured 17 radial velocities (RVs) of the giant over a period of 271 days. Fitting these RVs with a Keplerian model, we find an orbital period of P orb = 192.73 +/- 0.01 days and a companion mass function f(M 2) = 0.365 +/- 0.003 M circle dot. We detect ellipsoidal variability with the same period in optical light curves from the ASAS-SN survey. Joint fitting of the RVs, light curves, and the broadband spectral energy distribution allows us to robustly constrain the masses of both components. We find a giant mass of M star=0.99-0.03+0.02M circle dot and a companion mass of M2=1.23-0.03+0.05M circle dot , implying that the companion is a neutron star (NS). We recover a 4.06 hr period in the system's TESS light curve, which we tentatively associate with the NS spin period. The giant does not yet fill its Roche lobe, suggesting that current mass transfer is primarily via winds. Modules for Experiments in Stellar Astrophysics evolutionary models predict that the giant will overflow its Roche lobe in 5-10 Myr, eventually forming a recycled pulsar + white dwarf binary with a similar to 900 days period. IGR J16194-2810 provides a window on the future evolution of wide NS + main sequence binaries recently discovered via Gaia astrometry. As with those systems, the binary's formation history is uncertain. Before the formation of the NS, it likely survived a common envelope episode with a donor-to-accretor mass ratio greater than or similar to 10 and emerged in a wide orbit. The NS likely formed with a weak kick (v kick less than or similar to 50 km s-1), as stronger kicks would have disrupted the orbit.
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Abstract
Primitive arc magmas are more oxidized and enriched in sulfur-34 (34S) compared to mid-ocean ridge basalts. These findings have been linked to the addition of slab-derived volatiles, particularly sulfate, to arc magmas. However, the oxidation state of sulfur in slab fluids and the mechanisms of sulfur transfer in the slab remain inconclusive. Juxtaposed serpentinite and eclogitic metagabbro from the Voltri Massif (Italy) provide evidence for sulfur mobilization and associated redox processes during infiltration of fluids. Using bulk rock and in situ delta34S measurements, combined with thermodynamic calculations, we document the transfer of bisulfide-dominated, 34S-enriched fluids in equilibrium with serpentinite into adjacent metagabbro. We argue that the process documented in this study is pervasive along the subduction interface and infer that subsequent melting of these reacted slab-mantle interface rocks could produce melts that display the characteristic oxygen fugacity and sulfur isotope signatures of arc magmas worldwide.
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Abstract
Ethylene plays its essential roles in plant development, growth, and defense responses by controlling the transcriptional reprograming, in which EIN2-C-directed regulation of histone acetylation is the first key step for chromatin to perceive ethylene signaling. But how the nuclear acetyl coenzyme A (acetyl CoA) is produced to ensure the ethylene-mediated histone acetylation is unknown. Here we report that ethylene triggers the accumulation of the pyruvate dehydrogenase complex (PDC) in the nucleus to synthesize nuclear acetyl CoA to regulate ethylene response. PDC is identified as an EIN2-C nuclear partner, and ethylene triggers its nuclear accumulation. Mutations in PDC lead to an ethylene hyposensitivity that results from the reduction of histone acetylation and transcription activation. Enzymatically active nuclear PDC synthesizes nuclear acetyl CoA for EIN2-C-directed histone acetylation and transcription regulation. These findings uncover a mechanism by which PDC-EIN2 converges the mitochondrial enzyme-mediated nuclear acetyl CoA synthesis with epigenetic and transcriptional regulation for plant hormone response.
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Abstract
Organs that pump luminal fluids by the coordinated beat of motile cilia are integral to animal physiology. Such organs include the human airways, brain ventricles and reproductive tracts. Although cilia organization and duct morphology vary drastically in the animal kingdom, ducts are typically classified as carpet or flame designs. The reason behind the appearance of these two different designs and how they relate to fluid pumping remain unclear. Here, we demonstrate that two structural parameters-lumen diameter and cilia-to-lumen ratio-organize the observed duct diversity into a continuous spectrum that connects carpets to flames across all animal phyla. Using a unified fluid model, we show that carpets and flames represent trade-offs between flow rate and pressure generation. We propose that the convergence of ciliated organ designs follows functional constraints rather than phylogenetic distance and offer guiding design principles for synthetic ciliary pumps.
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