Lithium titanium oxide (Li4Ti5O12, LTO), a 'zero-strain' anode material for lithium-ion batteries, exhibits excellent cycling performance. However, its poor conductivity highly limits its applications. Here, the structural stability and conductivity of LTO were studied using in situ high-pressure measurements and first-principles calculations. LTO underwent a pressure-induced amorphization (PIA) at 26.9 GPa. The impedance spectroscopy revealed that the conductivity of LTO improved significantly after amorphization and that the conductivity of decompressed amorphous LTO increased by an order of magnitude compared with its starting phase. Furthermore, our calculations demonstrated that the different compressibility of the LiO6 and TiO6 octahedra in the structure was crucial for the PIA. The amorphous phase promotes Li+ diffusion and enhances its ionic conductivity by providing defects for ion migration. Our results not only provide an insight into the pressure depended structural properties of a spinel-like material, but also facilitate exploration of the interplay between PIA and conductivity.

The response of forsterite, Mg2SiO4, under dynamic compression is of fundamental importance for understanding its phase transformations and high-pressure behavior. Here, we have carried out an in situ X-ray diffraction study of laser-shocked polycrystalline and single-crystal forsterite (a-, b-, and c-orientations) from 19 to 122 GPa using the Matter in Extreme Conditions end-station of the Linac Coherent Light Source. Under laser-based shock loading, forsterite does not transform to the high-pressure equilibrium assemblage of MgSiO3 bridgmanite and MgO periclase, as has been suggested previously. Instead, we observe forsterite and forsterite III, a metastable polymorph of Mg2SiO4, coexisting in a mixed-phase region from 33 to 75 GPa for both polycrystalline and single-crystal samples. Densities inferred from X-ray diffraction data are consistent with earlier gas-gun shock data. At higher stress, the response is sample-dependent. Polycrystalline samples undergo amorphization above 79 GPa. For [010]- and [001]-oriented crystals, a mixture of crystalline and amorphous material is observed to 108 GPa, whereas the [100]-oriented forsterite adopts an unknown phase at 122 GPa. The first two sharp diffraction peaks of amorphous Mg2SiO4 show a similar trend with compression as those observed for MgSiO3 in both recent static- and laser-driven shock experiments. Upon release to ambient pressure, all samples retain or revert to forsterite with evidence for amorphous material also present in some cases. This study demonstrates the utility of femtosecond free-electron laser X-ray sources for probing the temporal evolution of high-pressure silicate structures through the nanosecond-scale events of shock compression and release.

We report the early discovery and multicolor (BVI) high-cadence light-curve analyses of the rapidly declining sub-Chandrasekhar Type Ia supernova KSP-OT-201509b (= AT 2015cx) from the KMTNet Supernova Program. The Phillips and color stretch parameters of KSP-OT-201509b are Delta M-B,M-15 1.62 mag and s(BV) 0.54, respectively, at an inferred redshift of 0.072. These, together with other measured parameters (such as the strength of the secondary I-band peak, colors, and luminosity), identify the source to be a rapidly declining Type Ia of a transitional nature that is closer to Branch-normal than 91bg-like. Its early light-curve evolution and bolometric luminosity are consistent with those of homologously expanding ejecta powered by radioactive decay and a Type Ia SN explosion with 0.32 0.01 M of synthesized Ni-56 mass, 0.84 0.12 M of ejecta mass, and (0.61 0.14) x 10(51) erg of ejecta kinetic energy. While its B - V and V - I colors evolve largely synchronously with the changes in the I-band light curve, as found in other supernovae, we also find the presence of an early redward evolution in V - I prior to -10 days since peak. The bolometric light curve of the source is compatible with a stratified Ni-56 distribution extended to shallow layers of the exploding progenitor. Comparisons between the observed light curves and those predicted from ejecta-companion interactions clearly disfavor Roche lobe-filling companion stars at large separation distances, thus supporting a double-degenerate scenario for its origin. The lack of any apparent host galaxy in our deep stack images reaching a sensitivity limit of similar to 28 mag arcsec(-2) makes KSP-OT-201509b a hostless Type Ia supernova and offers new insights into supernova host galaxy environments.

There has been considerable recent interest in the high-pressure behavior of silicon carbide, a potential major constituent of carbon-rich exoplanets. In this work, the atomic-level structure of SiC was determined through in situ X-ray diffraction under laser-driven ramp compression up to 1.5 TPa; stresses more than seven times greater than previous static and shock data. Here we show that the B1-type structure persists over this stress range and we have constrained its equation of state (EOS). Using this data we have determined the first experimentally based mass-radius curves for a hypothetical pure SiC planet. Interior structure models are constructed for planets consisting of a SiC-rich mantle and iron-rich core. Carbide planets are found to be similar to 10% less dense than corresponding terrestrial planets.

The Earth's fluid budget is dominated by species in the system C-O-H-N-S together with halogens such as F and Cl. H2O is by far the most abundant. Such fluids are one of the two main mass transport agents (fluid and magma) in the Earth. Among those, in particular aqueous fluids are efficient solvents of geochemically important components at high temperature and pressure. The solution capacity of aqueous fluids can be enhanced further by dissolved halogens and sulfur. CO2 or nitrogen species has the opposite effect.

The complexity of microbial communities suggests prevalent interactions involving more than just pairs of species. These so-called higher-order interactions may reveal new molecules that enable bacteria to deal with complex environments. This forum article discusses how higher-order interactions can be detected and why molecular biologists might care.

An outstanding goal in planetary science is to understand how terrestrial cores evolved to have the compositions, thermal properties, and magnetic fields observed today. To achieve that aim requires the integration of datasets from space missions with laboratory experiments conducted at high pressures and temperatures. Over the past decade, technological advances have enhanced the capability to conduct in situ measurements of physical properties on samples that are analogs to planetary cores. These challenging experiments utilize large-volume presses that optimize control of pressure and temperature, and diamond-anvil cells to reach the highest pressures. In particular, the current experimental datasets of density, compressional velocity, viscosity, and thermal conductivity of iron alloys are most relevant to the core conditions of small terrestrial planets and moons. Here we review the physical properties of iron alloys measured in the laboratory at conditions relevant to the cores of Mars, the Moon, and Mercury. We discuss how these properties inform models of core composition, as well as thermal and magnetic evolution of their cores. Experimental geochemistry (in particular, metal-silicate partitioning experiments) provides additional insights into the nature and abundance of light elements within cores, as well as crystallization processes. Emphasis is placed on the Martian core to discuss the effect of chemistry on core evolution.

Cells respond to physicalstimuli, such as stiffness1, fluid shear stress2 and hydraulic pressure3,4. Extracellular fluid viscosity is a key physical cue that varies under physiological and pathological conditions, such as cancer5. However, its influence on cancer biology and the mechanism by which cells sense and respond to changes in viscosity are unknown. Here we demonstrate that elevated viscosity counterintuitively increases the motility of various cell types on two-dimensional surfaces and in confinement, and increases cell dissemination from three-dimensional tumour spheroids. Increased mechanical loading imposed by elevated viscosity induces an actin-related protein 2/3 (ARP2/3)-complex-dependent dense actin network, which enhances Na+/H+ exchanger 1 (NHE1) polarization through its actin-binding partner ezrin. NHE1 promotes cell swelling and increased membrane tension, which, in turn, activates transient receptor potential cation vanilloid 4 (TRPV4) and mediates calcium influx, leading to increased RHOA-dependent cell contractility. The coordinated action of actin remodelling/dynamics, NHE1-mediated swelling and RHOA-based contractility facilitates enhanced motility at elevated viscosities. Breast cancer cells pre-exposed to elevated viscosity acquire TRPV4-dependent mechanical memory through transcriptional control of the Hippo pathway, leading to increased migration in zebrafish, extravasation in chick embryos and lung colonization in mice. Cumulatively, extracellular viscosity is a physical cue that regulates both short- and long-term cellular processes with pathophysiological relevance to cancer biology.

The Local Volume Mapper (LVM) project among the fifth iteration of the Sloan Digital Sky Survey (SDSS-V) plans to produce large integral-field spectroscopic survey data. The data will reveal the physical conditions of the interstellar medium in the Milky Way, the Magellanic Clouds, and other local-volume galaxies. We developed the Local Volume Mapper Spectrograph Control Package (LVMSCP) which controls the spectrograph subsystem. The architecture design of the software based on Python 3.9 follows a hierarchical structure composed of high-level, mid-level, low-level software packages, and hardware components. We used the new SDSS message passing protocol CLU for the interaction, based on RabbitMQ that implemented the Advanced Message Queuing Protocol (AMQP). The Actors that receive or produce messages to each other are also the units of the conceptual operation. Furthermore, the package applies asynchronous programming with non-blocking procedures since the three spectrographs should operate simultaneously. For requirement of the incremental code change and management in the collaboration of the developers, we adopted the SDSS Github Action which supports Continuous Integration (CI) / Continuous Deployment (CD). As a part of this, Unit testing with Pytest tests the individual components of a software respectively. Finally, the LVMSCP provides the Application Programming Interface (API) to the Robotic Observation Package (ROP) for the integrated observation to fulfill the required scientific survey execution for the spectrographs.