Latent heat method to detect melting and freezing of metals at megabar pressures
2021
PHYSICAL REVIEW MATERIALS
DOI
10.1103/PhysRevMaterials.5.033803
The high-pressure melting curves of metals provide simple and useful tests for theories of melting, as well as important constraints for the modeling of planetary interiors. Here, we present an experimental technique that reveals the latent heat of fusion of a metal sample compressed inside a diamond anvil cell. The technique combines microsecond-timescale pulsed electrical heating with an internally heated diamond anvil cell. Further, we use the technique to measure the melting curve of platinum to the highest pressure measured to date. Melting temperature increases from approximate to 3000 K at 34 GPa to approximate to 4500 K at 107 GPa, thermodynamic conditions that are between the steep and shallow experimental melting curves reported previously. The melting curve is a linear function of compression over the 0-20 % range of compression studied here, allowing a good fit to the Kraut-Kennedy empirical model with fit parameter C = 6.0.