Type Ib diamond formation and preservation in the West African lithospheric mantle: Re-Os age constraints from sulphide inclusions in Zimmi diamonds

Ten sulphide inclusions in three diamonds from the Zimmi (West Africa) alluvial diamond locality were analysed for their bulk Fe-Cu-Ni-Co contents and Re-Os isotopic compositions. The host diamonds are exceptionally rare, lb types that still preserve isolated nitrogen (C centres), rather than more common nitrogen pairs (A centres) and nitrogen aggregates (B centres). C centres in Zimmi diamonds require that they did not experience temperatures above 850 degrees C for any extended period. Such diamonds make up less than 0.1% of natural gem diamonds and have never before been dated. The sulphides are pyrrhotite-rich, have low Ni and Os contents, and radiogenic Os-187/Os-188, all features characteristic of eclogitic sulphides. Each diamond has 3-4 individual inclusions. Re-187/Os-188 and Os-187/Os-188 data fall along three individual similar to 650 Ma age arrays that represent essentially 3-point or 4-point mineral isochrons for each diamond unambiguously dating the time of diamond formation. The similar to 650 Ma age correlates with the timing of Neoproterozoic assembly of Gondwana, recorded in the Rokelide orogen along the SW margin of the West African craton. The initial Os-187/Os-188 of the three age arrays fall between 1.6 and 2.2 and are highly radiogenic compared to chondritic mantle at 650 Ma. Along with low Re/Os ratios, this data suggests that sulphides were not derived from Neoproterozoic subducting slabs, but rather from older eclogitic material already present in the West African lithospheric mantle. The age of the diamonds and their nitrogen substitutional characteristics, along with their residence in a lithospheric mantle with a normal cratonic geotherm (determined here from Koidu clinopyroxene xenocrysts) suggests that after diamond formation they were rapidly exhumed to shallower depths in the lithosphere. This likely occurred through tectonic uplift following Neoproterozoic continental collision. (C) 2016 Elsevier B.V. All rights reserved.