Geochemical data from MESSENGER have revealed details of Mercury's surface composition, showing that it differs from the other rocky planets in the inner solar system. For example, the planet's surface is enriched in S and C, and depleted in Fe, indicating that Mercury formed under much more reducing conditions than other planets. The surface is also enriched in Mg and depleted in Al and Ca. Observed elemental heterogeneities and percent levels of graphite suggest that Mercury underwent a magma ocean phase early in its history. These findings have important implications for understanding Mercury's origin and evolution.

We have found that individual presolar silicon carbide (SiC) dust grains from supernovae show a positive correlation between Ti-49 and Si-28 excesses, which is attributed to the radioactive decay of the short-lived (t(1/2) = 330 days) 49V to Ti-49 in the inner highly Si-28- rich Si/S zone. The V-49-Ti-49 chronometer shows that these supernova SiC dust grains formed at least 2 years after their parent stars exploded. This result supports recent dust condensation calculations that predict a delayed formation of carbonaceous and SiC grains in supernovae. The astronomical observation of continuous buildup of dust in supernovae over several years can, therefore, be interpreted as a growing addition of C-rich dust to the dust reservoir in supernovae.

Metamorphism is thought to destroy microfossils, partly through devolatilization and graphitization of biogenic organic matter. However, the extent to which there is a loss of molecular, elemental and isotope signatures from biomass during high-temperature metamorphism is not clearly established. We report on graphitic structures inside and coating apatite grains from the c. 1850 Ma Michigamme silicate banded iron formation from Michigan, metamorphosed above 550 degrees C. Traces of N, S, O, H, Ca and Fe are preserved in this graphitic carbon and X-ray spectra show traces of aliphatic groups. Graphitic carbon has an expanded lattice around 3.6 angstrom, forms microscopic concentrically-layered and radiating polygonal flakes and has homogeneous delta C-13 values around -22 parts per thousand, identical to bulk analyses. Graphitic carbon inside apatite is associated with nanometre-size ammoniated phyllosilicate. Precursors of these metamorphic minerals and graphitic carbon originated from ferruginous clay-rich sediments with biomass. We conclude that graphite coatings and inclusions in apatite grains indicate fluid remobilization during amphibolite-facies metamorphism of precursor biomass. This new evidence fills in observational gaps of metamorphosed biomass into graphite and supports the existence of biosignatures in the highly metamorphosed iron formation from the Eoarchean Akilia Association, which dates from the beginning of the sedimentary rock record.

We report Mo isotopic compositions of 37 presolar SiC grains of types Y (19) and Z (18), rare types commonly argued to have formed in lower-than-solar metallicity asymptotic giant branch (AGB) stars. Direct comparison of the Y and Z grain data with data for mainstream grains from AGB stars of close-to-solar metallicity demonstrates that the three types of grains have indistinguishable Mo isotopic compositions. We show that the Mo isotope data can be used to constrain the maximum stellar temperatures (T-MAX) during thermal pulses in AGB stars. Comparison of FRUITY Torino AGB nucleosynthesis model calculations with the grain data for Mo isotopes points to an origin from low-mass (similar to 1.5-3 M-circle dot) rather than intermediate-mass (> 3-similar to 9 M-circle dot) AGB stars. Because of the low efficiency of Ne-22(alpha, n)Mg-25 at the low T-MAX values attained in low-mass AGB stars, model calculations cannot explain the large Si-30 excesses of Z grains as arising from neutron capture, so these excesses remain a puzzle at the moment.

Here we report the relative degrees of thermal metamorphism for five Antarctic Ornans-like carbonaceous (CO) chondrites, including Dominion Range (DOM) 08006, as determined from the Cr-content of their FeO-rich (ferroan) olivine. These five CO3 chondrites complete the previously poorly-defined CO3.00 to 3.2 chondrite metamorphic trend. DOM 08006 appears to be a highly primitive CO chondrite of petrologic type 3.00. We report the detailed mineralogy and petrography of DOM 08006 using a coordinated, multi-technique approach.