Following the disruption of Russian natural gas flows to Europe, we investigate the impact of collaborative and selfish behavior of European countries to tackle energy scarcity and supply electricity, heat, and industrial gas to end users. We study how the operation of the European energy system will need to adapt to the disruption and identify optimal strategies to overcome the unavailability of Russian gas. Those strategies include diversifying gas imports, shifting energy generation to non-gas-based technologies, and reducing energy demands. Find-ings suggest that: (1) selfish behavior of Central European countries exacerbates the energy scarcity for many Southeastern European countries; (2) proactive collaborative energy savings, together with a mild winter, can fully relieve the stress of the gas shortage; (3) diversification of gas imports leads to bottlenecks in the gas network, especially in Southeastern Europe; and (4) electricity genera-tion is mostly shifted to coal-based power plants, causing higher carbon emissions.

Multi-energy systems can improve the performance of traditional energy systems, where energy carriers and sectors are decoupled, in terms of economic, environmental, and social sustainability, measured as the total cost of energy, emissions per energy demand, and self-sufficiency, respectively. This study assesses the impact that policy mechanisms can have in enabling these sustainability benefits. A mixed-integer linear problem is implemented, which optimizes the design and operation of multi-energy systems to minimize the total annual cost of supplying energy to residential end-users. Four policy types are tested for a Swiss case study, namely a feed-in tariff, an investment support mechanism, a carbon tax, and a regulation-based carbon cap. To assess how the policy impact varies between different end-users, we distinguish between passive consumers, that cannot access subsidies, and prosumers, who can. In our case study, subsidies, such as a feed-in tariff and an investment support mechanism, decrease the cost of energy for prosumers by up to 10%, but increase the cost for consumers by up to 33%, which points to the need of including energy equity considerations when designing policies. The carbon cap and the carbon tax impact all end-users equally, and tend to perform better in terms of reducing emissions. Emission reductions of up to 60% and 39% are observed for the carbon cap and carbon tax, respectively. The feed-in tariff and carbon cap perform best in fostering self-sufficiency and achieve balanced energy autonomy for high policy levels, revealing a trade-off between the different sustainability dimensions.

Designing decentralized energy systems in an optimal way can substantially reduce costs and environmental burdens. However, most models for the optimal design of multi-energy systems (MESs) exclude a comprehensive environmental assessment and consider limited technology options for relevant energy-intensive sectors, such as the industrial and mobility sectors. This paper presents a multi-objective optimization framework for designing MESs, which includes life cycle environmental burdens and considers a wide portfolio of technology options for residential, mobility, and industrial sectors. The optimization problem is formulated as a mixed integer linear program that minimizes costs and greenhouse gas (GHG) emissions while meeting the energy demands of given end-users. Whereas our MESs optimization framework can be applied for a large range of boundary conditions, the geographical island Eigeroy (Norway) is used as a showcase as it includes substantial industrial activities. Results demonstrate that, when properly designed, MESs are already cost-competitive with incumbent energy systems, and significant reductions in the amount of natural gas (92%) and GHG emissions (73%) can be obtained with a marginal cost increase (18%). Stricter decarbonization targets incur larger costs. A broad portfolio of technologies is deployed when minimizing GHG emissions and integrating the industrial sector. Environmental trade-offs are identified when considering the construction phase of energy technologies. Therefore, we argue that (i) MES designs and assessments require a thorough life cycle assessment beyond GHG emissions, and (ii) the entire life cycle should be considered when designing MESs, with the construction phase contributing up to 80% of specific environmental impact categories.

The maintenance and differentiation of highly potent animal stem cells generates an epigenetic cycle that underlies development. Drosophila female germline stem cells (GSC) produce cystoblast daughters that differentiate into nurse cells and oocytes. Developmental chromatin analysis profiling the differentiation of GSCs into cystoblasts and nCs of increasing ploidy shows that cystoblasts start developing by forming heterochromatin while in a transient syncytial state, the germline cyst, reminiscent of early embryonic cells. The open GSC chromatin state is further restricted by Polycomb repression of targets that include testis expressed genes briefly active in early female germ cells. like other highly potent stem cells, GSC metabolism is reprogrammed and Myc-dependent growth is upregulated by altering mitochondrial membrane transport, gluconeogenesis and other processes. Thus, the animal generational cycle comprises similar but distinct maternal and zygotic stem cell epigenetic cycles. We propose that the pluripotent stem cell state and daughter cell differentiation were shaped by the pressure to resist transposon activity over evolutionary time scales. In this GEO submission, we present data and analyses pertaining to H3K27ac, H3K27me3, and H3K9me3 ChIPseq, ATACseq, and RnAseq of Germline Stem Cells (GSCs) and nurse Cells (nCs) from Drosophila melanogaster ovaries.

Aubrites and enstatite chondrites (ECs) are isotopically similar to the Earth and therefore may resemble the primary materials that accreted to form our planet. Recent bulk H elemental and isotopic analyses of ECs and the Norton County aubrite suggest that enstatite-rich materials are H-rich and may represent a significant source of terrestrial water, with measured values of 3000 & PLUSMN;2000 & mu;g/g H2O and 5300 & PLUSMN;900 & mu;g/g H2O in the bulk and enstatite fractions of Norton County (Piani et al., Science, 2020). Here, we present a detailed investigation of in situ H2O concentrations in enstatite, diopside, forsterite, and plagioclase from a suite of main group aubrites, including Norton County, and Shallowater. We find that enstatite (4 & PLUSMN;2 & mu;g/g H2O), diopside (4.8 & PLUSMN;0.5 & mu;g/g H2O), and forsterite (5 & PLUSMN;3 & mu;g/g H2O) have similar H2O concentrations, and all are significantly lower than plagioclase (24 & PLUSMN;3 & mu;g/g H2O). We combine our in situ analyses of H2O contents with equilibrium partition coefficients and bulk mineralogies to estimate the bulk H2O content of our samples. We compare these first order estimates with bulk volatile analyses conducted using sample pyrolysis and find that the previous bulk H2O analyses of aubrites predominantly reflect terrestrial contamination and alteration. If our conclusion that the reported bulk H2O analyses of Norton County primarily reflect terrestrial contamination and alteration extends to bulk analyses of ECs, then EC-like material may not be a significant source of terrestrial water. Our results support the hypothesis that thermal metamorphism, melting, and differentiation leads to efficient desiccation of planetesimals relative to chondrites, and that differentiated planetesimals contributed, at most, trace amounts to Earth's water budget.& COPY; 2023 Elsevier B.V. All rights reserved.

The dominant benthic primary producers in coral reef ecosystems are complex holobionts with diverse microbiomes and metabolomes. In this study, we characterize the tissue metabolomes and microbiomes of corals, macroalgae, and crustose coralline algae via an intensive, replicated synoptic survey of a single coral reef system (Waimea Bay, OModified Letter Turned Commaahu, Hawaii) and use these results to define associations between microbial taxa and metabolites specific to different hosts. Our results quantify and constrain the degree of host specificity of tissue metabolomes and microbiomes at both phylum and genus level. Both microbiome and metabolomes were distinct between calcifiers (corals and CCA) and erect macroalgae. Moreover, our multi-omics investigations highlight common lipid-based immune response pathways across host organisms. In addition, we observed strong covariation among several specific microbial taxa and metabolite classes, suggesting new metabolic roles of symbiosis to further explore.

AgClO4 has been studied under compression by x-ray diffraction and density functional theory calculations. Experimental evidence of a structural phase transition from the tetragonal structure of AgClO4 to an orthorhombic barite-type structure has been found at 5.1 GPa. The transition is supported by total-energy calculations. In addition, a second transition to a monoclinic structure is theoretically proposed to take place beyond 17 GPa. The equation of state of the different phases is reported as well as the calculated Raman-active phonons and their pressure evolution. Finally, we provide a description of all the structures of AgClO4 and discuss their relationships. The structures are also compared with those of AgCl in order to explain the structural sequence determined for AgClO4.